مهندسی شیمی ایران

مهندسی شیمی ایران

ارزیابی اثر نانوذرات اکسید فلزی در الکترود پایه‌کربنی برای بررسی الکتروشیمیایی الکترود ابر خازن

نوع مقاله : مقاله پژوهشی

نویسندگان
1 دانشجوی دکتری مهندسی شیمی، دانشگاه تربیت مدرس
2 استادیار سیستمهای انرژی، دانشگاه صنعتی خواجه نصیرالدین طوسی
3 استاد مهندسی شیمی، دانشگاه تربیت مدرس
چکیده
پیشرفت در ابرخازن‌ها به‌عنوان یک وسیلۀ ذخیره‌سازی انرژی برجسته و پیشگام، توجه مجامع علمی و صنعتی را به‌خود جلب‌کرده‌است. در این زمینه، این مقالۀ تحقیقاتی از یک شگرد سنتز آسان، سریع و بسیار کارامد استفاده‌می‌کند که ظرفیت چشم‌گیری برای مقیاس‌پذیری صنعتی دارد. این مطالعه، بر سنتز یک الکترود حاوی نانو کامپوزیت CuCrO2 با نسبت‌های مختلف CuCrO2 و کربن سیاه (CB) و کربن فعال (AC) تمرکز دارد. ویژگی‌های نانوذرات و الکترودهای سنتزشده بااستفاده‌از تجزیه‌وتحلیل ساختاری و عملکردی ارزیابی‌شده‌است. تجزیه‌وتحلیل FESEM الکترودهای آماده‌شده، توزیع تقریباً یک‌نواختی از مواد را روی فوم نیکل به‌عنوان بستر الکترود نشان‌داد. در میان نمونه‌های کامپوزیت سنتزشده، بهترین عملکرد الکتروشیمیایی نشان‌داده‌شده مربوط‌به کامپوزیت حاوی 60 درصد وزنی CuCrO2 و 40 درصد وزنی مواد پایه‌کربنی است (ظرفیت ویژۀ F.g−1 700 و پایداری چرخۀ 91% پس از 5000 چرخه شارژ- دشارژ در A.g−1 1).
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Evaluation of the Effect of Metal Oxide Nanoparticles in Carbon-Based Electrodes for Electrochemical Investigation of Supercapacitor Electrodes

نویسندگان English

H. Kazemzadeh 1
M. Zamani Pedram 2
M. R. Omidkhah Nasrin 3
1 PhD Student of Chemical Engineering, Tarbiat Modares University
2 Assistant Professor of Energy Systems, K. N. Toosi University of Technology
3 Professor of Chemical Engineering, Tarbiat Modares University
چکیده English

Recent progress in supercapacitors—recognized as advanced and
high-potential energy storage devices—has drawn considerable interest from both scientific and industrial sectors. In this study,
a simple, rapid, and highly effective synthesis method is introduced, offering strong potential for scaling up to industrial production.
The research focuses on synthesizing an electrode containing CuCrO₂ nanocomposite using different proportions of CuCrO₂, carbon black (CB), and activated carbon (AC). The resulting nanoparticles and electrodes were analyzed through structural and performance-based assessments. FESEM imaging revealed that the electrode materials were evenly distributed across the nickel foam substrate. Among all the synthesized composites, the one combining CuCrO₂ (0.6 %wt) with a carbon-based material (0.4 %wt) delivered the best electrochemical performance, achieving a specific capacitance of 700 F.g⁻¹ and stability of 91% after 5000 charge-discharge cycles at a current density of 1 A.g⁻¹.

کلیدواژه‌ها English

Supercapacitor
CuCrO2
Carbon Black
Activated Carbon
Nanoparticle
Charge Storage
Energy Storage
Pseudo-Capacitor
Hybrid Energy Storage
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