مهندسی شیمی ایران

مهندسی شیمی ایران

حذف کاتیون مس از محلول‌های آبی بااستفاده‌از هیدروژل کامپوزیتی کربوکسی‌متیل‌سلولز/ ایتاکونیک اسید/ بنتونیت به‌وسیلۀ یک بستر جذب ثابت: مشخصه‌یابی و مطالعات سینتیک

نوع مقاله : مقاله پژوهشی

نویسندگان
1 کارشناس ارشد مهندسی شیمی، دانشگاه گیلان
2 دانشیار مهندسی شیمی، دانشگاه گیلان
چکیده
در این مطالعه، بااستفادهاز روش پلیمریزاسیون (بَسپارش) رادیکال آزاد هیدروژل کامپوزیتی برپایۀ کربوکسیمتیل سلولز/ ایتاکونیک اسید/بنتونیت تهیهشد و درادامه، توانایی این جاذب برای حذف یون مس (II) از محلول آبی بااستفادهاز یک ستون جذب بستر ثابت ارزیابیشد. نتایج آزمون طیفسنجی تبدیل فوریۀ فروسرخ، گروههای هیدروکسیل، کربوکسیلیک اسید و بنتونیت را در هیدروژل سنتزشده نشانداد. ریزنگارهای میکروسکوپ الکترونی روبشی بهخوبی حضور ذرات بنتونیت و جذب یون مس را به‌وسیلۀ هیدروژل نشانداد. بیشترین زمان تعادل و ظرفیت جذب در pH برابربا 5/5 به‌دستآمد. تأثیر مشخصه‌های ارتفاع جاذب (1/5، 2 و cm 3)، غلظت اولیۀ کاتیون مس (500، 750 و mg/L 1000) و سرعت خطی خوراک (3، 5/5 و mL/min 8) روی ظرفیت جذب، زمانهای فرسودگی و تعادل مس بررسیشد. نتایج نشانداد که حداکثر ظرفیت جذب تعادلی در ارتفاع cm 1/5، غلظت اولیۀ mg/L 500 و دبی mL/min 5/5 برابر mg/g 132 به‌دستآمد. بیشترین و کمترین زمان تعادل بهترتیب 204 و 22 دقیقه حاصلشد. از سه مدل سینتیکی (آدامز-بوهارت، توماس، BDST) برای برازش داده‌های تجربی استفادهشد؛ مدل آدامز- بوهارت و BDST بهترین تطابق را با دادههای آزمایشگاهی نشاندادند.
کلیدواژه‌ها

موضوعات


عنوان مقاله English

Copper Cation Removal from Aqueous Solutions Using Carboxymethyl Cellulose/ Itaconic Acid/ BentoniteComposite hydrogel by A Fixed Adsorption Column: Characterization and Kinetic Studies

نویسندگان English

.M Maleki Taleghani 1
.A Dadvand Koohi 2
1 M. Sc. in Chemical Engineering, University of Guilan
2 Associate Professor of Chemical Engineering, University of Guilan
چکیده English

In this study, a composite hydrogel based on carboxymethyl cellulose/itaconic acid/bentonite was prepared using the free radical polymerization method, and the ability of this adsorbent to remove copper (II) ions from an aqueous solution was evaluated using an adsorption column with a fixed bed. The results of infrared Fourier transform spectrometry showed the presence of hydroxyl, carboxylic acid, and bentonite groups in the synthesized hydrogel. Scanning electron microscope micrographs clearly showed the presence of bentonite particles and the adsorption of copper ions by the hydrogel.
The maximum equilibrium time and adsorption capacity were obtained at pH=5.5. The effect of the parameters of
(1.5, 2 and 3 cm), initial concentration of copper cation (500, 750 and 1000 mg/L) and linear feed speed (3, 5.5 and 8 mL/min) on adsorption capacity and breakthrough time was investigated. The obtained results showed that the maximum equilibrium adsorption capacity (132 mg/g) was obtained at a height of 1.5 cm, an initial concentration of 500 mg/L, and a flow rate of 5.5 mL/min. The maximum and minimum equilibrium time was 204 and 22 minutes, respectively. Three synthetic models (Adams-Bohart, Thomas, BDST) were used to fit the experimental data. Adams-Bohart model and BDST had the best fit with the experimental data.

کلیدواژه‌ها English

Adsorption
Hydrogel Composite
Carboxymethyl Cellulose
Itaconic Acid
Fixed Bed
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