[1] Nawaz, Z. (2015). Light alkane dehydrogenation to light olefin technologies: a comprehensive review. Reviews in chemical engineering, 31(5), 413-436.
[2] Maddah, H. A. (2018). A comparative study between propane dehydrogenation (PDH) technologies and plants in Saudi Arabia. Am. Sci. Res. J. Eng. Technol. Sci, 45(1), 49.
[3] Dai, Y., Gao, X., Wang, Q., Wan, X., Zhou, C., & Yang, Y. (2021). Recent progress in heterogeneous metal and metal oxide catalysts for direct dehydrogenation of ethane and propane. Chemical Society Reviews, 50(9), 5590-5630.
[4] Chen, S., Chang, X., Sun, G., Zhang, T., Xu, Y., Wang, Y., ... & Gong, J. (2021). Propane dehydrogenation: catalyst development, new chemistry, and emerging technologies. Chemical SOCIETY reviews, 50(5), 3315-3354.
[5] Yao, R., Herrera, J. E., Chen, L., & Chin, Y. H. C. (2020). Generalized mechanistic framework for ethane dehydrogenation and oxidative dehydrogenation on molybdenum oxide catalysts. ACS Catalysis, 10(12), 6952-6968.
[6] Sadrameli, S. M. (2015). Thermal/catalytic cracking of hydrocarbons for the production of olefins: A state-of-the-art review I: Thermal cracking review. Fuel, 140, 102-115.
[7] Sadrameli, S. M. (2016). Thermal/catalytic cracking of liquid hydrocarbons for the production of olefins: A state-of-the-art review II: Catalytic cracking review. Fuel, 173, 285-297.
[8] Batchu, S. P., Wang, H. L., Chen, W., Zheng, W., Caratzoulas, S., Lobo, R. F., & Vlachos, D. G. (2021). Ethane dehydrogenation on single and dual centers of ga-modified γ-Al2O3. ACS Catalysis, 11(3), 1380-1391.
[9] Carter, J. H., Bere, T., Pitchers, J. R., Hewes, D. G., Vandegehuchte, B. D., Kiely, C. J., ... & Hutchings, G. J. (2021). Direct and oxidative dehydrogenation of propane: from catalyst design to industrial application. Green Chemistry, 23(24), 9747-9799.
[10] Cavani, F., Koutyrev, M., Trifiro, F., Bartolini, A., Ghisletti, D., Iezzi, R., ... & Del Piero, G. (1996). Chemical and physical characterization of alumina-supported chromia-based catalysts and their activity in dehydrogenation of isobutane. Journal of catalysis, 158(1), 236-250.
[11] Zuo, C., & Su, Q. (2023). Research progress on propylene preparation by propane dehydrogenation. Molecules, 28(8), 3594.
[12] Vora, B. V. (2012). Development of dehydrogenation catalysts and processes. Topics in Catalysis, 55(19), 1297-1308.
[13] Won, W., Lee, K. S., Lee, S., & Jung, C. (2010). Repetitive control and online optimization of Catofin propane process. Computers & chemical engineering, 34(4), 508-517.
[14] Khanbolouk, F., & Yazdani, F. (2023). A Review of Platinum-Based Catalysts in the Dehydrogenation of Propane to Propylene. Iranian Chemical Engineering Journal, 22(130), 141-158, [In Persian].
[15] Sanfilippo, D., & Miracca, I. (2006). Dehydrogenation of paraffins: synergies between catalyst design and reactor engineering. Catalysis Today, 111(1-2), 133-139.
[16] Wei, S., Dai, H., Long, J., Lin, H., Gu, J., Zong, X., ... & Dai, Y. (2023). Nonoxidative propane dehydrogenation by isolated Co2+ in BEA zeolite: Dealumination-determined key steps of propane CH activation and propylene desorption. Chemical Engineering Journal, 455, 140726.
[17] Li, F. M., Yang, H. Q., Ju, T. Y., Li, X. Y., & Hu, C. W. (2012). Activation of propane CH and CC bonds by gas-phase Pt atom: a theoretical study. International Journal of Molecular Sciences, 13(7), 9278-9297.
[18] Sun, M. L., Hu, Z. P., Wang, H. Y., Suo, Y. J., & Yuan, Z. Y. (2023). Design strategies of stable catalysts for propane dehydrogenation to propylene. ACS Catalysis, 13(7), 4719-4741.
[19] Wang, H. Z., Sun, L. L., Sui, Z. J., Zhu, Y. A., Ye, G. H., Chen, D., ... & Yuan, W. K. (2018). Coke formation on Pt–Sn/Al2O3 catalyst for propane dehydrogenation. Industrial & Engineering Chemistry Research, 57(26), 8647-8654.
[20] Li, Q., Sui, Z., Zhou, X., Zhu, Y., Zhou, J., & Chen, D. (2011). Coke formation on Pt–Sn/Al2O3 catalyst in propane dehydrogenation: coke characterization and kinetic study. Topics in catalysis, 54, 888-896.
[21] Im, J., & Choi, M. (2016). Physicochemical stabilization of Pt against sintering for a dehydrogenation catalyst with high activity, selectivity, and durability. ACS Catalysis, 6(5),
2819-2826.
[22] Ren, G. Q., Pei, G. X., Ren, Y. J., Liu, K. P., Chen, Z. Q., Yang, J. Y., ... & Zhang, T. (2018). Effect of group IB metals on the dehydrogenation of propane to propylene over anti-sintering Pt/MgAl2O4. Journal of Catalysis, 366, 115-126.
[23] Ren, G., Xiong, S., Li, X., Lai, X., Chen, J., Chu, M., ... & Huang, S. (2024). Regeneration of sintered platinum at mild temperature for propane dehydrogenation. Journal of Catalysis, 429, 115276.
[24] Xie, L., Chai, Y., Sun, L., Dai, W., Wu, G., Guan, N., & Li, L. (2021). Optimizing zeolite stabilized Pt-Zn catalysts for propane dehydrogenation. Journal of Energy Chemistry, 57, 92-98.
[25] Sattler, J. J., Mens, A. M., & Weckhuysen, B. M. (2014). Real‐Time Quantitative Operando Raman Spectroscopy of a CrOx/Al2O3 Propane Dehydrogenation Catalyst in a Pilot‐Scale Reactor. ChemCatChem, 6(11), 3139-3145.
[26] Fridman, V. Z., Xing, R., & Severance, M. (2016). Investigating the CrOx/Al2O3 dehydrogenation catalyst model: I. identification and stability evaluation of the Cr species on the fresh and equilibrated catalysts. Applied Catalysis A: General, 523, 39-53.
[27] Fridman, V. Z., & Xing, R. (2017). Investigating the CrOx/Al2O3 dehydrogenation catalyst model: II. Relative activity of the chromium species on the catalyst surface. Applied Catalysis A: General, 530, 154-165.
[28] Sattler, J. J. H. B., Gonzalez-Jimenez, I. D., Mens, A. M., Arias, M., Visser, T., & Weckhuysen, B. M. (2013). Operando UV-Vis spectroscopy of a catalytic solid in a pilot-scale reactor: deactivation of a CrO x/Al2O3 propane dehydrogenation catalyst. Chemical Communications, 49(15), 1518-1520.
[29] Conley, M. P., Delley, M. F., Nunez-Zarur, F., Comas-Vives, A., & Coperet, C. (2015). Heterolytic activation of C–H bonds on CrIII–O surface sites is a key step in catalytic polymerization of ethylene and dehydrogenation of propane. Inorganic chemistry, 54(11), 5065-5078.
[30] Karami, H., & Soltanali, S. (2024). Enhanced catalytic performance with adjustable morphology and surface properties of alumina for propane dehydrogenation: Promote the catalytically active chromium sites, dispersion and anti-coking. Surfaces and Interfaces, 45, 103813.
[31] Sattler, J. J. H. B., Gonzalez-Jimenez, I. D., Mens, A. M., Arias, M., Visser, T., & Weckhuysen, B. M. (2013). Operando UV-Vis spectroscopy of a catalytic solid in a pilot-scale reactor: deactivation of a CrO x/Al2O3 propane dehydrogenation catalyst. Chemical Communications, 49(15), 1518-1520.
[32] Shee, D., & Sayari, A. (2010). Light alkane dehydrogenation over mesoporous Cr2O3/Al2O3 catalysts. Applied Catalysis A: General, 389(1-2), 155-164.
[33] Botavina, M. A., Evangelisti, C., Agafonov, Y. A., Gaidai, N. A., Panziera, N., Lapidus, A. L., & Martra, G. (2011). CrOx/SiO2 catalysts prepared by metal vapour synthesis: Physical–chemical characterisation and functional testing in oxidative dehydrogenation of propane. Chemical engineering journal, 166(3), 1132-1138.
[34] Fan, X., Li, J., Zhao, Z., Wei, Y., Liu, J., Duan, A., & Jiang, G. (2015). Dehydrogenation of propane over PtSn/SBA-15 catalysts: effect of the amount of metal loading and state. RSC Advances, 5(36), 28305-28315.
[35] He, D., Zhang, Y., Yang, S., Mei, Y., & Luo, Y. (2018). Investigation of the isolated Cr (VI) species in Cr/MCM‐41 catalysts and its effect on catalytic activity for dehydrogenation of propane. ChemCatChem, 10(23), 5434-5440.
[36] Nawaz, Z., Baksh, F., Zhu, J., & Wei, F. (2013). Dehydrogenation of C3–C4 paraffin's to corresponding olefins over slit-SAPO-34 supported Pt-Sn-based novel catalyst. Journal of Industrial and Engineering Chemistry, 19(2), 540-546.
[37] Zhang, Y., Yu, Y., Wang, R., Dai, Y., Bao, L., Li, M., ... & Li, H. (2023). Identifying the active site and structure–activity relationship in propane dehydrogenation over Ga2O3/ZrO2 catalysts. Journal of Catalysis, 428, 115208.
[38] Oliveira, A. S., Cueto, J., del Mar Alonso-Doncel, M., Kubů, M., Čejka, J., Serrano, D. P., & García-Muñoz, R. A. (2024). Propane dehydrogenation over Pt and Ga-containing MFI zeolites with modified acidity and textural properties. Catalysis Today, 427, 114437.
[39] Tan, S., Gil, L. B., Subramanian, N., Sholl, D. S., Nair, S., Jones, C. W., ... & Pendergast, J. G. (2015). Catalytic propane dehydrogenation over In2O3–Ga2O3 mixed oxides. Applied Catalysis A: General, 498, 167-175.
[40] Zhang, T., Pei, C., Sun, G., Chen, S., Zhao, Z. J., Sun, S., ... & Gong, J. (2022). Synergistic Mechanism of Platinum‐GaOx Catalysts for Propane Dehydrogenation. Angewandte Chemie, 134(35), e202201453.
[41] Szeto, K. C., Jones, Z. R., Merle, N., Rios, C., Gallo, A., Le Quemener, F., ... & Taoufik, M. (2018). A strong support effect in selective propane dehydrogenation catalyzed by Ga (i-Bu) 3 grafted onto γ-alumina and silica. ACS Catalysis, 8(8),7566-7577.
[42] Michorczyk, P., Kuśtrowski, P., Kolak, A., & Zimowska, M. (2013). Ordered mesoporous Ga2O3 and Ga2O3–Al2O3 prepared by nanocasting as effective catalysts for propane dehydrogenation in the presence of CO2. Catalysis Communications, 35,
95-100.
[43] Wu, J. L., Chen, M., Liu, Y. M., Cao, Y., He, H. Y., & Fan, K. N. (2013). Sucrose-templated mesoporous β-Ga2O3 as a novel efficient catalyst for dehydrogenation of propane in the presence of CO2. Catalysis communications, 30, 61-65.
[44] Sattler, J. J., Gonzalez‐Jimenez, I. D., Luo, L., Stears, B. A., Malek, A., Barton, D. G., ... & Weckhuysen, B. M. (2014). Platinum‐promoted Ga/Al2O3 as highly active, selective, and stable catalyst for the dehydrogenation of propane. Angewandte Chemie, 126(35), 9405-9410.
[45] Searles, K., Siddiqi, G., Safonova, O. V., & Copéret, C. (2017). Silica-supported isolated gallium sites as highly active, selective and stable propane dehydrogenation catalysts. Chemical science, 8(4), 2661-2666.
[46] Shao, C. T., Lang, W. Z., Yan, X., & Guo, Y. J. (2017). Catalytic performance of gallium oxide based-catalysts for the propane dehydrogenation reaction: effects of support and loading amount. RSC advances, 7(8), 4710-4723.
[47] Liu, G., Zhao, Z. J., Wu, T., Zeng, L., & Gong, J. (2016). Nature of the active sites of VO x/Al2O3 catalysts for propane dehydrogenation. ACS Catalysis, 6(8), 5207-5214.
[48] Ganduglia-Pirovano, M. V., Popa, C., Sauer, J., Abbott, H., Uhl, A., Baron, M., ... & Freund, H. J. (2010). Role of ceria in oxidative dehydrogenation on supported vanadia catalysts. Journal of the American Chemical Society, 132(7), 2345-2349.
[49] Sokolov, S., Bychkov, V. Y., Stoyanova, M., Rodemerck, U., Bentrup, U., Linke, D., ... & Kondratenko, E. V. (2015). Effect of Vox species and support on coke formation and catalyst stability in nonoxidative propane dehydrogenation. ChemCatChem, 7(11), 1691-1700.
[50] Rodemerck, U., Stoyanova, M., Kondratenko, E. V., & Linke, D. (2017). Influence of the kind of VOx structures in VOx/MCM-41 on activity, selectivity and stability in dehydrogenation of propane and isobutane. Journal of catalysis, 352, 256-263.
[51] Rodemerck, U., Sokolov, S., Stoyanova, M., Bentrup, U., Linke, D., & Kondratenko, E. V. (2016). Influence of support and kind of VOx species on isobutene selectivity and coke deposition in non-oxidative dehydrogenation of isobutane. Journal of Catalysis, 338, 174-183.
[52] Taghavinezhad, P., Haghighi, M., & Alizadeh, R. (2019). Influence of aging temperature and Mg/Zr molar ratio on transformation of C2 H6 to C2 H 4 over VO x catalyst supported on Mg–Zr nanocomposite. Research on Chemical Intermediates, 45, 1907-1927.
[53] Karami, H., Soltanali, S., Najafi, A. M., Ghazimoradi, M., Yaghoobpour, E., & Abbasi, A. (2023). Amorphous silica-alumina as robust support for catalytic dehydrogenation of propane: Effect of Si/Al ratio on nature and dispersion of Cr active sites. Applied Catalysis A: General, 658, 119167.
[54] Hu, P., Lang, W. Z., Yan, X., Chen, X. F., & Guo, Y. J. (2018). Vanadium-doped porous silica materials with high catalytic activity and stability for propane dehydrogenation reaction. Applied Catalysis A: General, 553, 65-73.
[55] Hu, P., Lang, W. Z., Yan, X., Chu, L. F., & Guo, Y. J. (2018). Influence of gelation and calcination temperature on the structure-performance of porous VOX-SiO2 solids in non-oxidative propane dehydrogenation. Journal of catalysis, 358, 108-117.
[56] Yang, Q. Q., Hu, P., Xiu, N. Y., Lang, W. Z., & Guo, Y. J. (2018). VOx/γ‐Al2O3 Catalysts for Propane Dehydrogenation Prepared by “Impregnation‐Solid Phase Reaction” Method with Aluminum Hydroxide as Support Precursor. ChemistrySelect, 3(35), 10049-10055.
[57] Zhao, Z. J., Wu, T., Xiong, C., Sun, G., Mu, R., Zeng, L., & Gong, J. (2018). Hydroxyl‐mediated non‐oxidative propane dehydrogenation over VOx/γ‐Al2O3 catalysts with improved stability. Angewandte Chemie International Edition, 57(23), 6791-6795.
[58] Yang, Z., Li, H., Zhou, H., Wang, L., Wang, L., Zhu, Q., ... & Xiao, F. S. (2020). Coking-resistant iron catalyst in ethane dehydrogenation achieved through siliceous zeolite modulation. Journal of the American Chemical Society, 142(38), 16429-16436.
[59] Hu, Z. P., Qin, G., Han, J., Zhang, W., Wang, N., Zheng, Y., ... & Liu, Z. (2022). Atomic insight into the local structure and microenvironment of isolated Co-motifs in MFI zeolite frameworks for propane dehydrogenation. Journal of the American Chemical Society, 144(27), 12127-12137.
[60] Perechodjuk, A., Zhang, Y., Kondratenko, V. A., Rodemerck, U., Linke, D., Bartling, S., ... & Kondratenko, E. V. (2020). The effect of supported Rh, Ru, Pt or Ir nanoparticles on activity and selectivity of ZrO2-based catalysts in non-oxidative dehydrogenation of propane. Applied Catalysis A: General, 602, 117731.
[61] Otroshchenko, T., Sokolov, S., Stoyanova, M., Kondratenko, V. A., Rodemerck, U., Linke, D., & Kondratenko, E. V. (2015). Ein unkonventionelles Katalysatorsystem auf der Basis von ZrO2 für die Propandehydrierung: Konzept, Synthese und aktive Zentren. Angewandte Chemie, 127(52), 16107-16111.
[62] Zhang, Y., Zhao, Y., Otroshchenko, T., Han, S., Lund, H., Rodemerck, U., ... & Kondratenko, E. V. (2019). The effect of phase composition and crystallite size on activity and selectivity of ZrO2 in non-oxidative propane dehydrogenation. Journal of Catalysis, 371, 313-324.
[63] Zhang, Y., Zhao, Y., Otroshchenko, T., Lund, H., Pohl, M. M., Rodemerck, U., ... & Kondratenko, E. V. (2018). Control of coordinatively unsaturated Zr sites in ZrO2 for efficient C–H bond activation. Nature communications, 9(1), 3794.
[64] Otroshchenko, T., Sokolov, S., Stoyanova, M., Kondratenko, V. A., Rodemerck, U., Linke, D., & Kondratenko, E. V. (2015). Ein unkonventionelles Katalysatorsystem auf der Basis von ZrO2 für die Propandehydrierung: Konzept, Synthese und aktive Zentren. Angewandte Chemie, 127(52), 16107-16111.
[65] Otroshchenko, T., Kondratenko, V. A., Rodemerck, U., Linke, D., & Kondratenko, E. V. (2017). ZrO2-based unconventional catalysts for non-oxidative propane dehydrogenation: Factors determining catalytic activity. Journal of Catalysis, 348, 282-290.
[66] Han, S., Zhao, Y., Otroshchenko, T., Zhang, Y., Zhao, D., Lund, H., ... & Kondratenko, E. V. (2019). Unraveling the Origins of the Synergy Effect between ZrO2 and CrO x in Supported CrZrO x for Propene Formation in Nonoxidative Propane Dehydrogenation. ACS Catalysis, 10(2), 1575-1590.
[67] Zhang, Y., Zhao, Y., Otroshchenko, T., Lund, H., Pohl, M. M., Rodemerck, U., ... & Kondratenko, E. V. (2018). Control of coordinatively unsaturated Zr sites in ZrO2 for efficient C–H bond activation. Nature communications, 9(1), 3794.
[68] Yun, J. H., & Lobo, R. F. (2014). Catalytic dehydrogenation of propane over iron-silicate zeolites. Journal of catalysis, 312, 263-270.
[69] Maeno, Z., Yasumura, S., Wu, X., Huang, M., Liu, C., Toyao, T., & Shimizu, K. I. (2020). Isolated indium hydrides in CHA zeolites: speciation and catalysis for nonoxidative dehydrogenation of ethane. Journal of the American Chemical Society, 142(10), 4820-4832.
[70] Sun, Y., Wu, Y., Shan, H., & Li, C. (2015). Studies on the nature of active cobalt species for the production of methane and propylene in catalytic dehydrogenation of propane. Catalysis Letters, 145, 1413-1419.
[71] Dai, Y., Gu, J., Tian, S., Wu, Y., Chen, J., Li, F., ... & Yang, Y. (2020). γ-Al2O3 sheet-stabilized isolate Co2+ for catalytic propane dehydrogenation. Journal of catalysis, 381, 482-492.
[72] Sun, Y., Wu, Y., Tao, L., Shan, H., Wang, G., & Li, C. (2015). Effect of pre-reduction on the performance of Fe2O3/Al2O3 catalysts in dehydrogenation of propane. Journal of Molecular Catalysis A: Chemical, 397, 120-126.
[73] Schweitzer, N. M., Hu, B., Das, U., Kim, H., Greeley, J., Curtiss, L. A., ... & Hock, A. S. (2014). Propylene hydrogenation and propane dehydrogenation by a single-site Zn2+ on silica catalyst. Acs Catalysis, 4(4), 1091-1098.
[74] Chen, M., Wu, J. L., Liu, Y. M., Cao, Y., Guo, L., He, H. Y., & Fan, K. N. (2011). Study in support effect of In2O3/MOx (M= Al, Si, Zr) catalysts for dehydrogenation of propane in the presence of CO2. Applied Catalysis A: General, 407(1-2), 20-28.
[75] Tan, S., Gil, L. B., Subramanian, N., Sholl, D. S., Nair, S., Jones, C. W., ... & Pendergast, J. G. (2015). Catalytic propane dehydrogenation over In₂O₃–Ga₂O₃ mixed oxides. Applied Catalysis. A, General, 498(C).
[76] Watanabe, R., Hirata, N., Miura, K., Yoda, Y., Fushimi, Y., & Fukuhara, C. (2019). Formation of active species for propane dehydrogenation with hydrogen sulfide co-feeding over transition metal catalyst. Applied Catalysis A: General, 587, 117238.
[77] Zhao, Y., Sohn, H., Hu, B., Niklas, J., Poluektov, O. G., Tian, J., ... & Hock, A. S. (2018). Zirconium modification promotes catalytic activity of a
single-site cobalt heterogeneous catalyst for propane dehydrogenation. ACS omega, 3(9), 11117-11127.
[78] Wang, W., Wu, Y., Liu, T., Zhao, Y., Qu, Y., Yang, R., ... & Wu, Y. (2022). Single Co sites in ordered SiO2 channels for boosting nonoxidative propane dehydrogenation. ACS Catalysis, 12(4), 2632-2638.
[79] Feliczak-Guzik, A. (2018). Hierarchical zeolites: Synthesis and catalytic properties. Microporous and Mesoporous Materials, 259, 33-45.
[80] Rimaz, S., Chen, L., Monzón, A., Kawi, S., & Borgna, A. (2021). Enhanced selectivity and stability of Pt-Ge/Al2O3 catalysts by Ca promotion in propane dehydrogenation. Chemical Engineering Journal, 405, 126656.
[81] Ponomaryov, A. B., Smirnov, A. V., Pisarenko, E. V., & Shostakovsky, M. V. (2022). Enhanced Pt dispersion and catalytic properties of NaCl-promoted Pt/MFI zeolite catalysts for propane dehydrogenation. Microporous and Mesoporous Materials, 339, 112010.
