مهندسی شیمی ایران

مهندسی شیمی ایران

بررسی آزمایشگاهی تأثیر نانوذرات اکسید آهن اصلاح ‌سطحی ‌شده با آسکوربیک‌اسید در فرایند ازدیاد برداشت نفت

نوع مقاله : مقاله پژوهشی

نویسندگان
1 دانشجوی کارشناسی ارشد مهندسی نفت، دانشگاه تربیت مدرس
2 دکترd مهندسی شیمی، دانشگاه تربیت مدرس
3 دانشیار گروه مهندسی نفت دانشکدۀ مهندسی شیمی، دانشگاه تربیت مدرس
چکیده
بررسی به‌کارگیری نانوذرات در فرایندهای ازدیاد برداشت نفت، موضوع مطالعات جدید پژوهشگران متعددی بوده‌است. در تحقیق پیشِ رو، روش هم‌رسوبی برای سنتز نانوذرات Fe3O4 به‌کار رفت. برای دست‌یابی به سوسپانسیون پایداری از نانوذرات سنتزشده در آب، از آسکوربیک‌اسید برای اصلاح سطحی آن‌ها استفاده شد و آزمون‌های مختلف شناسایی شامل آزمون‌ طیف­سنج فروسرخ تبدیل فوریه (FTIR) به‌منظور بررسی تشکیل گروه‌های عاملی مربوط‌ به مواد استفاده‌شده، میکروسکوپ الکترونی روبشی نشر میدانی به‌منظور مطالعۀ اندازۀ نانوذرات و ریخت‌شناسی آن‌ها، پتانسیل زتا به‌منظور بررسی بار سطحی نانوذرات سنتزشده، انجام شد. باتوجه‌به نتایج، اصلاح سطحی اندازۀ نانوذرات را افزایش داده‌است که البته این مقدار بسیار پایین گزارش شد. هم‌چنین باتوجه‌به نتایج آزمایش پتانسیل زتا اصلاح سطحی منجربه افزایش بار سطحی نانوذرات و درنتیجه منجربه پایداری نانوذرات در آب شده‌است. هم‌چنین آزمایش‌های سیلاب­زنی در میکرومدل برای بررسی تأثیر حضور نانوذرات در سیال تزریقی در فرایند ازدیاد برداشت نفت به‌کار رفت. میزان بازیافت نفت درحضور نانوذرات درمقایسه‌با عدم حضور آن­ها افزایش پیدا کرد و از 19/8 درصد به 30/9درصد- برای نانوذرۀ اکسید آهن اصلاح سطح شده بااستفاده‌از آسکوربیک اسید- رسید که افزایش 11 درصدی را نشان می­دهد.
کلیدواژه‌ها

موضوعات


عنوان مقاله English

Experimental Investigation of Modified Iron Oxide Nanoparticles with Ascorbic Acid on Enhanced Oil Recovery

نویسندگان English

M. R. Hasani 1
B. Sabzi Dizajyekan 2
A. Jafari 3
1 M. Sc. Student of Petroleum Engineering, Tarbiat Modares University
2 Ph. D. in Chemical Engineering, Tarbiat Modares University
3 Associate Professor of Petroleum Engineering, Tarbiat Modares University
چکیده English

The application of nanoparticles in Enhanced Oil Recovery (EOR) processes is one of the most widely used methods in recent studies by researchers. In this study, Fe3O4 nanoparticles were synthesized using the co-precipitation method. In order to stabilize the suspension of synthesized nanoparticles in water, the nanoparticles were surface modified using ascorbic acid. Various identification tests were performed. Fourier transform infrared spectroscopy (FTIR) to investigate the formation of functional groups, field emission scanning electron microscopy (FESEM) to evaluate the morphology and size of nanoparticles and zeta potential to investigate the surface charge of synthesized nanoparticles. According to the results, surface modification has increased the size of nanoparticles, although this amount was reported to be very low. Also, following the test results of zeta potential, surface modification has increased the surface charge of nanoparticles and as a result has led to the stability of nanoparticles in water. Also, to study the effect of the presence of nanoparticles in the injected fluid in the EOR process, flooding experiments were performed in micromodel. The oil recovery factor in the presence of nanoparticles increased from 19.8% for water flood to 30.9% for surface-modified iron oxide nanoparticles using ascorbic acid, which shows an increase of 11%.
 

کلیدواژه‌ها English

Enhanced Oil Recovery (EOR)
Iron Oxide Nanoparticle
Ascorbic Acid
Surface Modification
Micromodel
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