روش‌های ساخت ذرات پلیمری متخلخل: آخرین دستاوردها

نوع مقاله : مقاله مروری

نویسنده

استادیار مهندسی پلیمر، دانشگاه یزد

چکیده

ذرات پلیمری متخلخل حاوی حفره‌های داخلی و خارجی و از مساحت ویژۀ بسیار زیاد، چگالی نسبتاً کم، نفوذپذیری و قابلیت جذب عالی برخوردار هستند. ساختار حفره‌ها (تخلخل، اندازۀ حفره، مساحت ویژه) از عوامل اصلی حاکم بر کاربرد این‌گونه مواد در زمینه‌های مختلف کاتالیست، جداسازی،استخراج فاز جامد، تبادل یونی، حسگرها، ذخیره و رهایش داروست. کاربردهای گستردۀ ذرات متخلخل محققان را وادار به توسعۀ روش‌های متداول مانند پلیمریزاسیون تعلیقی، پراکنشی، رسوبی، تورم دانه‌ای و روش­های جدید امولسیون غشایی / میکروکانال، میکروسیال می‌کند. در تمامی این روش‌ها از عوامل تخلخل مختلف در مرحلۀ اول و به‌دنبال آن حذف عامل تخلخل‌ساز برای تولید حفره‌ها استفاده می­شود. در این مطالعه همۀ روش‌های گوناگون پلیمریزاسیون برای تهیۀ ذرات پلیمری متخلخل (مزو،میکرو، ماکرو) با ساختار کروی، غیر کروی و عامل‌دار مرور شده و برتری‌ها و کاستی‌های هر روش از نظر خواص ذره ذکر شده است.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Techniques for Preparation of Porous Polymer Particles: Recent Achievements

نویسنده [English]

  • Z. Daneshfar
Assistant Professor of Polymer Engineering, Yazd University
چکیده [English]

Porous polymer particles containing internal and external pores have a very large specific area, relatively low density, permeability and excellent adsorption capacity. The structure of pores (porosity, pore size, specific area) are the main factors governing the application of such materials in various catalyst fields, separation, solid phase extraction, ion exchange, sensors storage and drug delivery. Extensive applications of porous particles are forcing researchers to develop conventional methods such as suspension polymerization, dispersion, precipitation, seed sweeling polymerization and new membrane / microchannel and microfluidic emulsification methods.
In all these methods, different porogen are used in the first stage, followed by the removal of the porogen to produce pores. In this study, all different polymerization techniques for the preparation of porous polymer particles with spherical and non-spherical structure, functionality are reviewed and the advantages and disadvantages of each method in terms of particle properties and particle size distribution are mentioned.
 

کلیدواژه‌ها [English]

  • Porous Polymer Particles
  • Seed Swelling Polymerization
  • Heterogenous Polymerization
  • Membrane / Microchannel Emulsification
  • Microfluidic Emulsification

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مهندسی شیمی ایران
دوره 21، شماره 122 - شماره پیاپی 122
مرداد و شهریور 1401
صفحه 35-51

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