مهندسی شیمی ایران

مهندسی شیمی ایران

بررسی کارایی غشای PVDF/Cellulose/nano MgO در حذف آموکسی‌سیلین از محلول‌های آبی

نوع مقاله : مقاله پژوهشی

نویسندگان
1 دانشجوی کارشناسی ارشدشیمی، گروه شیمی، دانشکدۀ علوم پایه، واحد اهر، دانشگاه آزاد اسلامی، اهر، ایران
2 دانشیار شیمی، گروه شیمی، دانشکدۀ علوم پایه، واحد اهر، دانشگاه آزاد اسلامی، اهر، ایران
3 مرکز تحقیقات نانوفناوری صنعتی، واحد تبریز، دانشگاه آزاد اسلامی، تبریز، ایران
چکیده
حذف آنتی‌بیوتیک‌ها از آب آلوده بهدلیل اثرات زیان‌آور آنها بر محیط‌زیست و موجودات زنده بسیار مهم است. در این تحقیق، یک غشای پلیمری برپایۀ پلی‌وینیلیدین فلوراید بااستفادهاز ترسیب سلولز و نانوذرات اکسید منیزیم (PVDF/Cellulose/MgO) برروی آن تهیه شد. غشای تهیهشده بااستفادهاز میکروسکوپ الکترونی روبشی نشر میدانی، پراش پرتو ایکس، میکروسکوپ نیروی اتمی و اندازه‌گیری زاویۀ تماس شناسایی شد. کارایی غشای تهیهشده به‌عنوان جاذب برای حذف آموکسی‌سیلین به‌عنوان آلایندۀ مدل بررسی شد و اثر pH، غلظت آموکسی‌سیلین و زمان بر حذف آموکسی‌سیلین مطالعه شد. نتایج نشان داد که با کاهش pH، کاهش غلظت اولیۀ آموکسی‌سیلین و افزایش زمان تماس، درصد حذف آموکسی‌سیلین افزایش می‌یابد و 85% از حذف آموکسی‌سیلین در غلظت 200 میلی‌گرم بر لیتر از آموکسی‌سیلین،3 = pH و مدت ‌زمان 100 دقیقه بهدست آمد. سینتیک حذف آموکسی‌سیلین نیز بااستفادهاز غشای PVDF/Cellulose/MgO بررسی شد. نتایج تأیید کرد که غشای PVDF/Cellulose/MgO یک جاذب بالقوه برای حذف آموکسی‌سیلین از آب آلوده است.
کلیدواژه‌ها

موضوعات


عنوان مقاله English

Evaluation of PVDF /Cellulose /Nano MgO Membrane Efficiency in Removal of Amoxicillin from Aqueous Solutions

نویسندگان English

S. Birang 1
P. Gharbani 2 3
1 M. Sc. Student of Chemistry, Ahar Branch, Islamic Azad University, Ahar, Iran
2 Associate Professor of Chemistry, Ahar Branch, Islamic Azad University, Ahar, Iran
3 Industrial Nanotechnology Research Center, Tabriz Branch, Islamic Azad University, Tabriz, Iran
چکیده English

Removal of antibiotics from water resources is essential for their harmful effects on living organisms. In this work, a polymeric membrane based on polyvinylidene fluoride deposited by cellulose loaded with Magnesium oxide nanoparticles (PVDF /Cellulose/MgO) has been prepared.
The prepared membrane was characterized using FESEM, XRD, AFM, and contact angle measurement. The efficiency of the prepared membranes as an adsorbent for removing amoxicillin as a model pollutant was investigated. The effect of pH, amoxicillin concentration, and the time on the removal of amoxicillin was studied. The results showed that with a decrease in pH, a reduction in the initial concentration of amoxicillin, and an increase in time, the percentage of amoxicillin removal increases, and the maximum percentage of amoxicillin removal was obtained at about 85% at 200 mg/liter of amoxicillin, pH = 3, and 100 min. The kinetic of amoxicillin removal using PVDF/Cellulose/MgO membrane was also investigated. These results confirmed that PVDF/Cellulose/MgO membrane would be a potential adsorbent for removing amoxicillin from contaminated water.

کلیدواژه‌ها English

Membrane
Amoxicillin
Polyvinylidene Fluoride
Magnesium Oxide Nanoparticles
 [1]        Porrang, S., Rahemi, N., Davaran, S., Mahdavi, M., & Hassanzadeh, B. (2021). Synthesis of High Biocompatible Mesoporous Silica Nanocarriers with Regular and Uniform Pore Distribution for Doxorubicin Drug Delivery. Iranian Chemical Engineering Journal, 20(115), 31-42.
[2]        Zhu, J., Tian, M., Zhang, Y., Zhang, H., & Liu, J. (2015). Fabrication of a novel “loose” nanofiltration membrane by facile blending with
Chitosan–Montmorillonite nanosheets for dyes purification. Chemical Engineering Journal, 265, 184-193.
[3]        Mosavi, S. S., Zare, E. N., Behniafar, H., & Tajbakhsh, M. (2023). Removal of amoxicillin antibiotic from polluted water by a magnetic bionanocomposite based on carboxymethyl tragacanth gum-grafted-polyaniline. Water, 15(1), 202.
[4]        Homem, V., & Santos, L. (2011). Degradation and removal methods of antibiotics from aqueous matrices–a review. Journal of environmental management, 92(10), 2304-2347.
[5]        Kümmerer, K. (2001). Drugs in the environment: emission of drugs, diagnostic aids and disinfectants into wastewater by hospitals in relation to other sources–a review. Chemosphere, 45(6-7), 957-969.
[6]        Mehrizad, A., & Gharbani, P. (2016). Removal of methylene blue from aqueous solution using
nano-TiO2/UV process: optimization by response surface methodology. Progress in Color, Colorants and Coatings, 9(2), 135-143.
[7]        Gharbani, P. (2017). Synthesis of polyaniline‑tin (II) molybdophosphate nanocomposite and application of it in the removal of dyes from aqueous solutions. Journal of Molecular Liquids, 242, 229-234.
[8]        Gasemloo, S., Sohrabi, M. R., Khosravi, M., Dastmalchi, S., & Gharbani, P. (2016). Fabrication of sulfated nanofilter membrane based on carboxymethyl cellulose. Water Science and Technology, 74(11), 2611-2619.
[9]        Khezerlou, S., Babazadeh, M., Mehrizad, A., Gharbani, P., & Es' haghi, M. (2021). Preparation of hydroxyapatite-calcium ferrite composite for application in loading and sustainable release of amoxicillin: optimization and modeling of the process by response surface methodology and artificial neural network. Ceramics International, 47(17), 24287-24295.
[10]      Fard, B. H., Khojasteh, R. R., & Gharbani, P. (2018). Preparation and characterization of visible-light sensitive nano Ag/Ag 3 VO 4/AgVO 3 modified
by graphene oxide for photodegradation of reactive orange 16 dye. Journal of Inorganicand Organometallic Polymers and Materials, 28, 1149-1157.
[11]      Davoudi Darzi, S., Hashmi Nasr, F., Sadeghi, F., & Khalili-Garakani, A. (2022). Application of Membrane Processes in Supply and Development of Sustainable Water and Energy in Country. Iranian Chemical Engineering Journal, 21(121), 33-54.
[12]      Saadat, M. M., Norouzbahari, S., & Esmaeili, M. (2021). An insight into hollow fiber membrane contactor technology and its position in separation of carbon dioxide gas. Iran. Chem. Eng. J., 20(118), 66-77.
[13]      Sun, M., Cui, M., Wang, Y., Fan, X., & Song, C. (2020). Enhanced permeability and removal efficiency for phenol and perfluorooctane sulphonate by a multifunctional CNT/Al2O3 membrane with electrochemical assistance. Journal of Nanoscience and Nanotechnology, 20(9), 5951-5958.
[14]      Wang, F., Chen, Z., Zhu, Z., & Guo, J. (2022). Construction of visible light responsive ZnO/Ng-C3N4 composite membranes for antibiotics degradation. Journal of Materials Research and Technology, 17, 1696-1706.
[15]      Wu, H., Niu, X., Yang, J., Wang, C., & Lu, M. (2016). Retentions of bisphenol A and norfloxacin by three different ultrafiltration membranes in regard to drinking water treatment. Chemical engineering journal, 294, 410-416.
[16]      Guo, D., Liu, Y., Ji, H., Wang, C. C., Chen, B., Shen, C., ... & Liu, W. (2021). Silicate-enhanced heterogeneous flow-through electro-Fenton system using iron oxides under nanoconfinement. Environmental Science & Technology, 55(6), 4045-4053.
[17]      Choi, K. J., Kim, S. G., & Kim, S. H. (2008). Removal of antibiotics by coagulation and granular activated carbon filtration. Journal of hazardous materials, 151(1), 38-43.
[18]      Xing, Z. P., & Sun, D. Z. (2009). Treatment of antibiotic fermentation wastewater by combined polyferric sulfate coagulation, Fenton and sedimentation process. Journal of Hazardous Materials, 168(2-3), 1264-1268.
[19]      Košutić, K., Furač, L., Sipos, L., & Kunst, B. (2005). Removal of arsenic and pesticides from drinking water by nanofiltration membranes. Separation and Purification Technology, 42(2), 137-144
[20]      Hassanzadeh, P., Gharbani, P., Derakhshanfard, F., & Memar Maher, B. (2021). Preparation and characterization of PVDF/gC 3 N 4/chitosan polymeric membrane for the removal of direct blue 14 dye. Journal of Polymers and the Environment, 29, 3693-3702.
[21]      Siyal, S. H., Javed, M. S., Ahmad, A., Sajjad, M., Batool, S., Khan, A. J., Akram, Sh., Alothman, A. A., Alshgari, R. A., & Najam, T. (2021). Free-standing 3D Co3O4@ NF micro-flowers composed of porous ultra-long nanowires as an advanced cathode material for supercapacitor. Current Applied Physics, 31, 221-227.
[22]      Datta, J., & Nandi, A. K. (1997). Cocrystallization of poly (vinylidene fluoride) and vinylidene fluoride-tetrafluoro-ethylene copolymer blends: 3. Structural study. Polymer, 38(11), 2719-2724.
[23]      Okada, D., Kaneko, H., Kato, K., Furumi, S., Takeguchi, M., & Yamamoto, Y. (2015). Colloidal crystallization and ionic liquid induced partial β-phase transformation of poly (vinylidene fluoride) nanoparticles. Macromolecules, 48(8), 2570-2575.
[24]      Cai, X., Lei, T., Sun, D., & Lin, L. (2017). A critical analysis of the α, β and γ phases in poly (vinylidene fluoride) using FTIR. RSC advances, 7(25), 15382-15389.
[25]      Park, S., Baker, J. O., Himmel, M. E., Parilla, P. A., & Johnson, D. K. (2010). Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance. Biotechnology for biofuels, 3, 1-10.
[26]      Chau, T. T. (2009). A review of techniques for measurement of contact angles and their applicability on mineral surfaces. Minerals engineering, 22(3), 213-219.
[27]      Abdulsalam, M., Che Man, H., Goh, P. S., Yunos, K. F., Zainal Abidin, Z., Isma MI, A., & Ismail, A. F. (2020). Permeability and antifouling augmentation
of a hybrid PVDF-PEG membrane using nano-magnesium oxide as a powerful mediator for POME decolorization. Polymers, 12(3), 549.
[28]      Moussavi, G., Alahabadi, A., Yaghmaeian, K., & Eskandari, M. (2013). Preparation, characterization and adsorption potential of the NH4Cl-induced activated carbon for the removal of amoxicillin antibiotic from water. Chemical engineering journal, 217, 119-128.
[29]      Lin, Y. C., Liu, K. M., Chiu, P. L., Chao, C. M., Wen, C. S., Wang, C. Y., & Tseng, H. H. (2022). Enhancing the hydrophilicity and biofoulant removal ability of a PVDF ultrafiltration membrane via π-π interactions as measured by AFM. Journal of Membrane Science, 641, 119874.
[30]      Park, J. A., Nam, A., Kim, J. H., Yun, S. T., Choi, J. W., & Lee, S. H. (2018). Blend-electrospun graphene oxide/Poly (vinylidene fluoride) nanofibrous membranes with high flux, tetracycline removal and anti-fouling properties. Chemosphere, 207, 347-356.
[31]      Guo, J., Farid, M. U., Lee, E. J., Yan, D. Y. S., Jeong, S., & An, A. K. (2018). Fouling behavior of negatively charged PVDF membrane in membrane distillation for removal of antibiotics from wastewater. Journal of Membrane Science, 551,12-19.
[32]      Popa, A., Toloman, D., Stefan, M., Petran, A., Macavei, S., Ulinici, S., ... & Pana, O. (2021). Hybrid PVDF-P (L-DOPA)-ZnO membranes for dyes and antibiotics removal through simultaneous action of adsorption and photocatalysis processes. Journal of Environmental Chemical Engineering, 9(6), 106812.
[33]      Mohammed, A. A., Al-Musawi, T. J., Kareem, S. L., Zarrabi, M., & Al-Ma'abreh, A. M. (2020). Simultaneous adsorption of tetracycline, amoxicillin, and ciprofloxacin by pistachio shell powder coated with zinc oxide nanoparticles. Arabian Journal of Chemistry, 13(3), 4629-4643.