Iranian Chemical Engineering Journal

Iranian Chemical Engineering Journal

Studying the Effect of Adsorption Process Variables on Adsorption Capacity and Removal Percentage of Toluene from Aqueous Solutions by Magnetic Hydroxyapatite Nanoparticles

Document Type : Original Article

Authors
1 M. Sc. Student of Materials Engineering, Materials and Energy Research Center
2 Associate Professorof Materials Engineering, Materials and Energy Research Center
3 Assistant Professor of Materials Engineering, Shahrood University of Technology
4 Professor of Materials Engineering, Materials and Energy Research Center
5 Professor of Chemistry, Materials and Energy Research Center
Abstract
The presence of toluene in industrial effluents is one of the most dangerous environmental pollutants, which is considered one of the factors that destroy the environment. There are several methods for removing toluene from aqueous solutions. One of the methods to remove toluene from aqueous solutions is adsorption. In recent years, magnetic hydroxyapatite has been proposed as an adsorbent for the separation of pollutants in aqueous solutions, due to its magnetic separation properties and the possibility of reuse. In this research, magnetic hydroxyapatite was synthesized using co-precipitation method and then toluene adsorption was investigated using magnetic hydroxyapatite nanoparticles. The structure and phase analysis of the synthesized nano-adsorbent were investigated using scanning electron microscope (SEM) and X-ray diffraction (XRD), respectively. An UV spectrophotometer was used to investigate the change in toluene concentration, and a scanning electron microscope and X-ray diffraction spectroscopy were used to investigate the microstructure and chemical composition before and after toluene adsorption. In this research, with using magnetic hydroxyapatite nanoparticles, the highest percentage of toluene removal and the highest adsorption capacity was 6.75% and 980 mg/g, respectively.
The results showed that the synthesized magnetic hydroxyapatite nanoparticles have the ability to adsorb toluene from aqueous solutions and can be introduced as an adsorbent of this organic compound.
Keywords
Subjects

[1]        Babaei, A. A., Ahmadi, K., Kazeminezhad, I., Alavi, S. N., & Takdastan, A. (2016). Synthesis and Application of Magnetic Hydroxyapatite for Removal of Tetracycline from Aqueous Solutions. Journal of Mazandaran University of Medical Sciences, 26: 146-159.
[2]        Watkinson, A. J., Murby, E. J., & Costanzo, S. D. (2007). Removal of antibiotics in conventional and advanced wastewater treatment: implications for enviromental discharge and wastewater recycling. Water Research, 41: 4164-4176.
[3]        Babaei, A. A., Mesdaghinia, A. R., Haghighi, N. J., Nabizadeh, R., & Mahvi, A. H. (2011). Modeling of nonylphenol degradation by photo-nanocatalytic process via multivariate approach. Journal of Hazardous Materials, 185(2-3): 1237-1279.
[4]        Irannajad, M., Soleimanpour, M., & Haghighi, H. K. (2019). Adsorption and kinetics studies of heavy metals removal by MnO2 modified zeolite.
New Process in Material Engineering, 13(1): 1-11.
[5]        Gholinia Ahangar, H., (2011). Removal of toluene from waste water by non-uniform electrocoagulation. MSc Thesis, Babol University of Technology (Noshirvani), Babol, Iran.
[6]        Berger, R., (1998). Koaleszenzprobleme in Chemischen Prozessen. Chemie Ingenieur Technik, 58: 51-67.
[7]        Karimi Takanlu, L., Farazadkia, M., Mahvi, A. H., Esrafily, A., & Golshan, M. (2014). Optimization of adsorption process of Cadmium ions from synthetic wastewater using synthesized iron magnetic nanoparticles (Fe3O4). Iranian Journal of Health and Environment, 7: 1-3.
[8]        Afkhami, A., Madrakian, T., Ahmadi, R., Bagheri, H., & Tabatabaee, M. (2011). Chemically modified alumina nanoparticles for selective solid phase extraction and preconcentration of trace amount of Cd(II). Microchimica Acta, 175(1-2): 69-77.
[9]        Fouladi fard, R., & Ebrahimi, A. A., (2011). Effciency study of nickle (II) biosorption by powder of waste activated sluge from aqueous solution. Iranian Journal of Haelth and Environment, 3(4): 419-30.
[10]      Zhang, X., Gao, B., Elise Creamer, A., Cao, C., & Li, Y., (2017). Adsorption of VOCs onto engineered carbon materials: A review. Journal of Hazardous Materials, 338: 102-123.
[11]      Yang, C., Miao, G., Pi, Y., Qibin Xia, Q., Wu, J., Li, Z., & Xiao, J., (2019). Abatement of various types of VOCs by adsorption/catalytic oxidation: A review. Chemical Engineering Journal, 370: 1128-1153.
[12]      Noormohammadi, M., Faghihi, M., & Zabihi, M., (2022). Design and Synthesis of Ceramic Nanocomposites on Modified Gamma Alumina Substrate to Remove Organic Contaminants from Wastewater. Iranian Chemical Engineering Journal, 21: 85-100, In Persian.
[13]      Wang, J., Wu, Z., Niu, Q., Liu, L., Yang, L., Fu, M., Ye, D., & Chen, P., (2021). Highly efficient adsorptive removal of toluene using silicon-modified activated carbon with improved fire resistance. Journal of Hazardous Materials, 415: 125753.
[14]      Gan, G., Fan, S., Li, X., Zhang, Z., & Hao, Z., (2023). Adsorption and membrane separation for removal and recovery of volatile organic compounds. Journal of Environmental Sciences, 123: 96-115.
[15]      Li, J., Liu, L., Jalil Shah, S., Tang, Y., Jiang, S., Mu, G., Man, Q., Zhao, Z., & Zhao, Z., (2023). Construction of novel Heat-conducting Cu-based MOF nanocomposite (HK-mBNNS/PVDF) film for highly efficient Ad-/desorption of toluene. Chemical Engineering Journal, 456: 140964.
[16]      Schwarzenbach, R. P., Escher, B. I., Fenner, K., Hofstetter, T. B., & Johnson, C. A., (2006). The challenge of micropollutants in aquatic systems. Science, 313: 1027-77.
[17]      Saad, L., (2009). Water pollution Americans. top green concern.
[18]      Heisler, J., Glibert, P. M., Burkholder, J. M., Anderson, D. M., & Cochlan, W. (2008). Eutrophication and harmful algal blooms: a scientific consensus. Harmful Algae, 8: 3–13.
[19]      Kouhkanzadeh, S., Mobasherpour, I., Molaei, M. J., Salahi, E., & Pazouki, M. (2020). Effect of Heat Treatment on Grain Growth of Magnetic Nanocrystalline Hydroxyapatite Powder. Advanced Ceramics Progress, 6: 15-21.
[20]      Kohkanzadeh, S., (2019). Removal Toluene from aqueous solutions by nano crystalline magnetic hydroxyapatite. MSc Thesis, Materials and Energy Research Center, Karaj, Iran.
[21]      Mobasherpour, I., Salahi, E., & Pazouki, M. (2011). Removal of divalent cadmium cations by means of synthetic nano crystallite hydroxyapatite. Desalination, 266: 142-148.
[22]      Lillo-Ródenas, M. A., Cazorla-Amorós, D., & Linares-Solano, A. (2005). Behaviour of activated carbons with different pore size distributions and surface oxygen groups for benzene and toluene adsorption at low concentrations. Carbon, 43: 1758-1767.
[23]      Wang, X., Ma, C., Xiao, J., Xia, Q., Wu, J., & Li, Z. (2018). Benzene/toluene/water vapor adsorption and selectivity of novel C-PDA adsorbents with high uptakes of benzene and toluene. Chemical Engineering Journal, 335: 970-978.
[24]      Mao, H., Zhou, D., Hashisho, Z., Wang, S., Chen, H., Wang, H., & Lashaki, M. J. (2015). Microporous activated carbon from pinewood and wheat straw by microwave-assisted KOH treatment for the adsorption of toluene and acetone vapors. RSC Advances, 5: 36051-36058.
[25]      Li, Y., Miao, J., Sun, X., Xiao, J., Li, Y., Wang, H., Xia, Q., & Li, Z. (2016). Mechanochemical synthesis of Cu-BTC@GO with enhanced water stability and toluene adsorption capacity. Chemical Engineering Journal, 298: 191-197.
[26]      Vellingiri, K., Kumar, P., Deep, A., & Kim, K. H. (2017). Metal-organic frameworks for the adsorption of gaseous toluene under ambient temperature and pressure. Chemical Engineering Journal, 307: 1116-1126.