Design and Synthesis of Ceramic Nanocomposites on Modified Gamma Alumina Substrate to Remove Organic Contaminants from Wastewater

Document Type : Original Article

Authors

1 M. Sc. in Chemical Engineering, Sahand University of Technology

2 Assistant Professor of Niroo Research Institute

3 Associate Professor of Chemical Engineering, Sahand University of Technology

Abstract

In the present study, three-component alumina-chitosan-clay nanocomposite (Al/Cs/C) using in situ polymerization method was evaluated as an efficient and a low-cost adsorbent for the removal of methyl orange dye as an anionic contaminant from aqueous solutions. Activated alumina is a porous mineral adsorbent that was selected as the substrate of the nanocomposite. In order to improve the physical properties of alumina and make an environmentally friendly adsorbent, chitosan biopolymer was used as a composite reinforcement. In continued, the clay particles were applied to increase the adsorption capacity of the adsorbent and modification of the composite. The various structural analysis including X ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and field emission scanning electron microscopy (FESEM) were evaluated to study the morphology of the fabricated samples. The highest adsorption capacity for the prepared adsorbent was 133.33 mg/g, according to Langmuir isotherm. There is a good agreement between the pseudo second order kinetics and the experimental data.

Keywords

Main Subjects


[1]        Khan, M. A., Ghouri, A. M., "Environmental pollution: its effects on life and its remedies", Researcher World: Journal of Arts, Science & Commerce, Vol. 2, pp. 276-285, (2011).
[2]        Kant, R., "Textile dyeing industry an environmental hazard", Natural Science, Vol. 4, pp. 22-26, (2011).
[3]        Edition, F., "Guidelines for drinking-water quality," WHO chronicle, Vol. 38, pp. 104-108, (2011).
[4]        Behbudi, G., Shayesteh, K., "Heavy Metal Removal Methods from Water and Wastewater: A Review Study", Environmental Health, Vol. 6, pp. 145-160, (2020).
[5]        H. Masoomie,  R. Jamshidian,  H. Ghanadzadeh Gilani, B. Abbasi Souraki, "Adsorption of Valeric Acid from Aqueous Solution Onto the Activated Carbon", iranian journal of chemical engineering, Vol. 19, pp. 19-32, In Persian, (2020).
[6]        Omanović-Mikličanin, E., Badnjević, A., Kazlagić, A., Hajlovac, M., "Nanocomposites: A brief review", Health and Technology, Vol. 10, pp. 51-59, (2020).
[7]        Zheng, Y., Duan, Y., Tang, H., Li, C., Li, J., Zhu, C., Liu, S., "Experimental research on selective adsorption of gaseous mercury (II) over SiO2, TiO2 and γ-Al2O3", Fuel, Vol. 237, pp. 202-208, (2019).
[8]        Sun, C., Tian, P., Tian, J., Shen, S., Pang, H., Ye, J., Ning, G., "Magnetic mesoporous γ-Al2O3/ZnFe2O4 micro-bowls realizing enhanced adsorption, separation and recycle performance towards waste water", Microporous and Mesoporous Materials, Vol. 270, pp. 120-126, (2018).
[9]        Pourshadlou, S., Mobasherpour, I., Majidian, H., Salahi, E., Bidabadi, F. S., Mei, C.-T., Ebrahimi, M., "Adsorption system for Mg2+ removal from aqueous solutions using bentonite/γ-alumina nanocomposite", Journal of colloid and interface science, Vol. 568, pp. 245-254, (2020).
[10]      Di Natale, F., Carotenuto, C., D’Addio, L., Jaworek, A., Krupa, A., Szudyga, M., Lancia, A., "Capture of fine and ultrafine particles in a wet electrostatic scrubber", Journal of Environmental Chemical Engineering, Vol. 3, pp. 349-356, (2015).
[11]      Gu, S. H., Nicolas, V., Lalis, A., Sathirapongsasuti, N., Yanagihara, R., "Complete genome sequence and molecular phylogeny of a newfound hantavirus harbored by the Doucet’s musk shrew (Crocidura douceti) in Guinea", Infection, Genetics and Evolution, Vol. 20, pp. 118-123, (2013).
[12]      Mao, H., Wei, C., Gong, Y., Wang, S., Ding, W., "Mechanical and water-resistant properties of eco-friendly chitosan membrane reinforced with cellulose nanocrystals", Polymers, Vol. 11, p. 166, (2019).
[13]      Hirase, R., Higashiyama, Y., Mori, M., Takahara, Y., Yamane, C., "Hydrated salts as both solvent and plasticizer for chitosan", Carbohydrate Polymers, Vol. 80, pp. 993-996, (2010).
[14]      Sahariah, P., Masson, M., "Antimicrobial chitosan and chitosan derivatives: a review of the structure–activity relationship", Biomacromolecules, Vol. 18, pp. 3846-3868, (2017).
[15]      Berger, J., Reist, M., Mayer, J. M., Felt, O., Gurny, R., "Structure and interactions in chitosan hydrogels formed by complexation or aggregation for biomedical applications", European journal of pharmaceutics and biopharmaceutics, Vol. 57, pp. 35-52, (2004).
[16]      Denkbaş, E., Seyyal, M., Pişkin, E., "Implantable 5-fluorouracil loaded chitosan scaffolds prepared by wet spinning", Journal of membrane Science, Vol. 172, pp. 33-38, (2000).
[17]      Gogoi, P., Thakur, A. J., Devi, R. R., Das, B., Maji, T. K., "A comparative study on sorption of arsenate ions from water by crosslinked chitosan and crosslinked chitosan/MMT nanocomposite", Journal of Environmental Chemical Engineering, Vol. 4, pp. 4248-4257, (2016).
[18]      Hashemi, S. J., Neves, M., Nakajima, M., "Effects of chitosan/nanoclay bentonite on the mechanical properties, water permeability and microstructure of nanocomposite film", Journal of Food Processing and Preservation, Vol. 10, pp. 33-46, (2018).
[19]      Yu, L., Luo, Y. -M., "The adsorption mechanism of anionic and cationic dyes by Jerusalem artichoke stalk-based mesoporous activated carbon", Journal of Environmental Chemical Engineering, Vol. 2, pp. 220-229, (2014).
[20]      Bahrudin, N., Nawi, M., "Mechanistic of photocatalytic decolorization and mineralization of methyl orange dye by immobilized TiO2/chitosan-montmorillonite", Journal of Water Process Engineering, Vol. 31, p. 100843, (2019).
[21]      Zhang, J., Zhou, Q., Ou, L., "Kinetic, isotherm, and thermodynamic studies of the adsorption of methyl orange from aqueous solution by chitosan/alumina composite", Journal of Chemical & Engineering Data, Vol. 57, pp. 412-419, (2012).
[22]      Kang, S., Qin, L., Zhao, Y., Wang, W., Zhang, T., Yang, L., Rao, F., Song, S., "Enhanced removal of methyl orange on exfoliated montmorillonite/chitosan gel in presence of methylene blue", Chemosphere, Vol. 238, p. 124693, (2020).
[23]      Gandhi, M. R., Viswanathan, N., Meenakshi, S., "Preparation and application of alumina/chitosan biocomposite", International Journal of Biological Macromolecules, Vol. 47, pp. 146-154, (2010).
[24]      Ebadollahzadeh, H., Zabihi, M., "Competitive adsorption of methylene blue and Pb (II) ions on the nano-magnetic activated carbon and alumina", Materials Chemistry and Physics, Vol. 248, p. 122893, (2020).
[25]      A Wahab, J., Derman, M., "Characterization of Porous Anodic Aluminium Oxide Film on Aluminium Templates Formed in Anodizing Process", Advanced Materials Research, Vol. 173, pp. 55-60, 01/01 (2011).
[26]      Han, Y. -S., Lee, S. -H., Choi, K., Park, I., "Preparation and characterization of chitosan-clay nanocomposites with antimicrobial activity", Journal of Physics and Chemistry of Solids, Vol. 71, pp. 464-467, 04/01 (2010).
[27]      Li, W. -Y., Liu, J., Chen, H., Deng, Y., Zhang, B., Wang, Z., Zhang, X., Hong, S., "Application of oxalic acid cross-linking activated alumina/chitosan biocomposites in defluoridation from aqueous solution. Investigation of adsorption mechanism", Chemical Engineering Journal, Vol. 225, pp. 865–872, 06/01 (2013).
[28]      Islam, M. M., Khan, M. N., Biswas, S., Choudhury, T. R., Haque, P., Rashid, T. U., Rahman, M. M., "Preparation and characterization of bijoypur clay-crystalline cellulose composite for application as an adsorbent", Adv. Mater. Sci, Vol. 2, (2017).
[29]      Islam, M., Khan, M. N., Biswas, S., Choudhury, T., Haque, P., Rashid, T., Rahman, M., "Preparation and Characterization of Bijoypur clay(Kaolinite)-crystalline cellulose composite for application as an adsorbent", Vol. 2, pp. 1-7, 07/20 (2017).
[30]      Azzam, E., Eshaq, G., Rabie, A., Bakr, A. -S., Abd-Elaal, A. A., Metwally, A. E., Tawfik, S., "Preparation and Characterization of Chitosan-Clay Nanocomposites for the Removal of Cu (II) from Aqueous Solution", International Journal of Biological Macromolecules, Vol. 89, 05/01 (2016).
[31]      Shahnavazi, P., Pourabdollah, K., Treatment of Quaternary Solution of Water/ Ethanol/ Acetaldehyde/ Acetic Acid by Activated Carbon Bed, iranian journal of chemical engineering, Vol. 19, pp. 63-73, In Persian, (2020).
[32]      Zabihi, M., Ahmadpour, A., Asl, A. H., "Removal of mercury from water by carbonaceous sorbents derived from walnut shell", Journal of Hazardous materials, Vol. 167, pp. 230-236, (2009).
[33]      Kyzas, G. Z., Bikiaris, D. N., Mitropoulos, A. C., "Chitosan adsorbents for dye removal: a review", Polymer International, Vol. 66, pp. 1800-1811, (2017).
[34] Neisi, A., Vosoughi Niri, M., Asadi, A., Mohammadi, M., Shirmardi, M., Fazlzadehdavilb, M., "Removal of Acid Red 14 by Nano-Alumina and Micro-Alumina Powder From Aqueous Solution", Journal of Sabzevar University of Medical Sciences, Vol. 23, pp. 479-489, 10/10 (2016).