ORIGINAL_ARTICLE
تأثیر کاستی جایشناختی بر ظرفیت ذخیرهسازی هیدروژن اتم ایتریم نشاندار شده برروی گرافن متخلخل
ظرفیت ذخیرهسازی هیدروژن با استفادهاز اتم ایتریم (Y) نشاندارشده بر روی گرافن متخلخل ((PG1 از راه محاسبات نظریۀ تابعی چگالی (DFT)2 بررسیشد. در اینبررسی از گرافن متخلخل بهدلیل تقارن جایشناختی استفادهشد. محاسبات نشانداد که پایدارترین مکان برای جذب اتم ایتریم روی گرافن متخلخل، مرکز حلقۀ هگزاگونال کربن است. سازوکارهای قطبش و پیوندزنی، هردو به جذب اتم ایتریم روی گرافنهای متخلخل کمک میکنند. تجزیهوتحلیل چگالی بار، نشانداد که حضور اتم ایتریم در مقایسهبا افزایش اندازۀ منافذ، نقش مؤثرتری در افزایش انرژی جذب مولکول هیدروژن دارد. در مقایسهبا جذب مولکول هیدروژن روی گرافن خالص، کاستی جایشناختی مانند تخلخل میتواند حالت رسانایی بیشتری در سطح انرژی فرمی ایجاد کند و جذب مولکول هیدروژن روی گرافن متخلخل افزایش مییابد. حداکثر چهار مولکول هیدروژن میتوانند روی سامانۀ Y-PGs جذب شوند. بیشترین میانگین انرژی جذب مربوط به گرافن متخلخل با اندازۀ منافذ بزرگتر با میانگین انرژی جذب 513/0 الکترون ولت است.
https://www.ijche.ir/article_119019_a82e40f528009ea578f86aa5ab69dfd7.pdf
2020-10-22
6
15
گرافن متخلخل
ذخیرهسازی هیدروژن
نظریۀ تابعی چگالی (DFT)
فاطمه
یساره
1
دانشگاه پیام نور-اردکان
AUTHOR
علی
کاظم پور
kazempour@pnu.ac.ir
2
مسول پژوهشکده پوشش های نانو ساختار
LEAD_AUTHOR
رضا
بهجت منش اردکانی
3
دانشگاه پیام نور-اردکان
AUTHOR
[1] Xia, Y., Yang, Z., Zhu, Y., "Porous carbon-based materials for hydrogen storage: advancement and challenges", Journal of Materials Chemistry A, 1,
1
pp. 9365-9381, (2013).
2
[2] Chen, Y., Wang, J., Yuan, L., Zhang, M., Zhang, C., "Sc-Decorated Porous Graphene for High-Capacity Hydrogen Storage: First-Principles Calculations", Materials, 10, p. 894, (2017).
3
[3] Ao, Z., Dou, S., Xu, Z., Jiang, Q., Wang, G., "Hydrogen storage in porous graphene with Al decoration," international journal of hydrogen energy, 39, pp. 16244-16251, (2014).
4
[4] Liu, W., Liu, Y., Wang, R., "Prediction of hydrogen storage on Y-decorated graphene: A density functional theory study", Applied Surface Science, 296, pp. 204-208, (2014).
5
[5] Chen, Y., Wang, J., Yuan, L., Zhang, M., Zhang, C., "Sc-Decorated Porous Graphene for High-Capacity Hydrogen Storage: First-Principles Calculations", Materials, 10, p. 894, (2017).
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[6] Zhao, Y., Kim, Y. H., Dillon, A. C., Heben, M. J., Zhang, S. B. "Hydrogen storage in novel organometallic buckyballs. Physical review letters", 94(15), p. 155504, (2005).
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[7] Huang, C., Wu, H., Deng, K., Tang, W., Kan, E., "Improved permeability and selectivity in
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porous graphene for hydrogen purification",
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Physical Chemistry Chemical Physics, 16(47),
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pp. 25755-25759, (2014).
11
[8] Bieri, M., Treier, M., Cai, J., Aït-Mansour, K., Ruffieux, P., Gröning, O. Müllen, K., "Porous graphenes: two-dimensional polymer synthesis with atomic precision", Chemical communications, (45), pp. 6919-6921, (2009).
12
[9] Ao, Z., Dou, S., Xu, Z., Jiang, Q., Wang, G., "Hydrogen storage in porous graphene with Al decoration", International journal of hydrogen energy, 39(28), pp. 16244-16251, (2014).
13
[10] Li, Y., Zhou, Z., Shen, P., Chen, Z.,
14
"Two-dimensional polyphenylene: experimentally available porous graphene as a hydrogen purification membrane", Chem. Commun. 46: pp. 3672–3674, (2010)
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[11] Yuan, L., Wang, D., Gong, J., Zhang, C., Zhang, L., Zhang, M., Kang, L., "First-principles study of
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V-decorated porous graphene for hydrogen storage", Chemical Physics Letters, 726, pp. 57-61, (2019).
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20
Y-decorated porous graphene", Applied Surface Science, 399, pp. 463-468, (2017).
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23
ORIGINAL_ARTICLE
مقایسۀ نتایج مدلهای شبکۀ عصبی مصنوعی با مدلهای ریاضی مختلف برای تخمین نرخ نم در فرایند خشککردن میوۀ به
در این پژوهش، فرایند خشککردن میوۀ به و تأثیر مشخصههای مختلفی مانند سرعت هوای خشککردن، زمان، دما و ضخامت بر نسبت نم، مطالعه و بررسی شد. 7 مدل ریاضی بر دادههای به دست آمده از 27 سری آزمایش برازش و بهترین مدل انتخاب شد. همچنین مدلسازی با شبکۀ عصبی مصنوعی (ANN) انجام گرفت. در این مدلسازی، اثر تمام مشخصههای ورودی در فرایند خشککردن بهطور همزمان بررسی شد. ساختار شبکۀ انتخابی از نوع پرسپترون چندلایه با الگوریتم پس انتشار خطا در نظر گرفته شد. با پژوهش روی تعداد مختلفی از نرونهای لایۀ میانی و نیز توابع انتقال مختلف، از 9 نرون و تابع انتقال لگاریتم سیگموئیدی برای لایۀ میانی و تابع انتقال پیورلین برای لایۀ خروجی استفاده شد. مدلسازی با شبکۀ عصبی مصنوعی،اثر همزمانچهارمشخصۀورودی را با دقت بسیار بالایی پیشبینی کرد. نتایج نشان داد که مدلسازی ANN در مقایسه با بهترین مدل ریاضی دارای دقت بالاتری است.
https://www.ijche.ir/article_119020_a48ec2a878eda53ec303b8c63dd4d25e.pdf
2020-10-22
16
29
شبکۀ عصبی مصنوعی
نسبت نم
مدل ریاضی
عباس
خوشحال
abbas.khoshhal@gmail.com
1
دانشگاه پیام نور
AUTHOR
حمید
یزدانی
h.yazdan@chmail.ir
2
دانشگاه پیام نور
LEAD_AUTHOR
نیره السادات
موسوی
ns-mousavi@irdci.ac.ir
3
پژوهشکده توسعه صنایع شیمیایی
AUTHOR
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in a convective dryer", J. Food Process Eng., 32,
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ORIGINAL_ARTICLE
مطالعه و بررسی مؤلفههای فرایند استخراج حلالی کبالت از محلول کلریدی با استفاده از مخلوط عاملهای کمپلکسساز Cyanex272، TBP و TOPO
در این تحقیق، فرایند استخراج کبالت از محلول کلریدی با استفاده از مخلوط استخراجکنندههای TBp ، TOPO و Cyanex272 بررسی شد. مؤلفههای فرایندی مانند اثر pH محلول آبی، غلظت استخراجکنندهها، نسبت فاز آبی به آلی و بازیابی با غلظتهای مختلف اسید سولفوریک در استخراج کبالت بررسی شدند. نتایج آزمایشها نشان داد که مخلوط حاصل از استخراجکنندههای TBp ، TOPO و Cyanex272 با غلظت بهترتیب برابر با 2/0، 1/0 و 3/0 مول بر لیتر برای استخراج بهینۀ کبالت با درصد استخراج بالای 39/91% مناسب است. اسید سولفوریک با غلظت یک مول بر لیتر بهعنوان یک واکنشگر مناسب در بازیابی محلول بهکار گرفته شد که درصد بازیابی آن بالای 2/99% بهدست آمد. در این مطالعه، یک سامانۀ همافزایی مخلوط گزارش شد که در جداسازی یونهای فلزی بسیار مؤثر است و میتواند در بازیابی باتریهای لیتیومی با روش هیدرومتالورژی بهکار گرفته شود.
https://www.ijche.ir/article_119021_a586e2758f8ef9a447f73a10545d8961.pdf
2020-10-22
30
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کبالت
استخراج حلالی
همافزایی
مؤلفههای فرایندی
مخلوط استخراجکنندهها
رضوان
ترکمان
rtorkaman@aeoi.org.ir
1
هیات علمی در پژوهشکده چرخه سوخت هسته ای، سازمان انرژی اتمی
AUTHOR
مهدی
اسداله زاده
mehdiasadollahzadeh@aeoi.org.ir
2
هیات علمی در پژوهشکده چرخه سوخت هسته ای، سازمان انرژی اتمی
LEAD_AUTHOR
[1] Asadollahzadeh, M., Torkaman, R., Torab-Mostaedi, M., "Extraction and Separation of Rare Earth Elements by Adsorption Approaches: Current Status and Future Trends". Sep. Purif. Rev., Article in
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Press (2020), DOI:10.1080/15422119.2020.1792930, (2020).
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[2] توحیدی، م، "فلزات استراتژیک: مواد اولیه و شیوههای تولید، کارایی و کاربرد، عرضه و تقاضا، درجۀ بحرانی و آسیبپذیری"، جهاد دانشگاهی دانشگاه تهران، (1388).
3
[3] Davis, J. R., "Nickel, Cobalt, and Their Alloys", ASM Specialty Handbook, UK, (2000).
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[4] Swain, B., Cho, S. S., Lee, G. H., Lee, C. G., Uhm, S., "Extraction/Separation of Cobalt by Solvent Extraction: A Review", Appl. Chem. Eng. 26:
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pp. 631-639, (2015).
6
[5] Swain, B., Shimand, H. W., Lee, C. G., "Extraction/Separations of Cobal.t by Supported Liquid Membrane: A Review", Korean Chem. Eng. Res., 57: pp. 313-320, (2019)
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[6] Juang, R., Kao, H., "Extraction separation of Co(II)/Ni(II) from concentrated HCl solutions in rotating disc and hollow-fiber membrane contactors", Sep. Purif. Technol., 42, pp. 65-73, (2005).
8
[7] Torkaman, R., Asadollahzadeh, M., Torab-Mostaedi, M., Maragheh-Ghannadi, M.," Reactive extraction of cobalt sulfate solution with D2EHPA/TBP extractants in the pilot plant Oldshue–Rushton column", Chem. Eng. Res. Des., 120: pp. 58-68, (2017).
9
[8] Torkaman, R., Asadollahzadeh, M., Torab-Mostaedi, M., Maragheh-Ghannadi, M., "Recovery of cobalt from spent lithium ion batteries by using acidic and basic extractants in solvent extraction process", Sep. Purif. Technol., 186: pp. 318-325, (2017).
10
[9] Suzuki, T., Nakamura, T., Inoue, Y., Niinae, M., Shibata, J., "A hydrometallurgical process for the separation of aluminum, cobalt, copper and lithium in acidic sulfate media", Sep. Purif. Technol., 98:
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pp. 396-401, (2012).
12
[10] Grigorieva, N. A., Fleitlikh, I. Y., "Cobalt extraction from sulfate media with bis(2,4,4-trimethylpentyl)dithiophosphinic acid in the presence of electron donor additives", Hydrometallurgy, 138: pp. 71-78, (2013)
13
[11] Nadimi, H., Amirjani, A., Fatmehsari, D. H., Firoozi, S., Azadmehr, A. "Effect of tartrate ion on extraction behavior of Ni and Co via D2EHPA in sulfate media", Miner. Eng., 69: pp.177-184, (2014).
14
[12] Wieszczycka, K., Wojciechowska, A., Krupa, M., "Equilibrium and mechanism of cobalt(II) extraction from chloride solution by hydrophobic
15
2-pyridineketoxime", Sep. Purif. Technol., 142:
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pp. 129-136, (2015).
17
[13] Mondal, S., Kumar, V., Sharma, J. N., Hubli, R. C., Suri, A. K., "Evaluation of n-octyl(phenyl)phosphinic acid (OPPA) as an extractant for separation of cobalt(II) and nickel(II) from sulphate solutions", Sep. Purif. Technol., 89: pp. 66-70, (2012).
18
[14] Zhang, W., Pranolo, Y., Urbani, M., Cheng, C. Y., "Extraction and separation of nickel and cobalt with hydroxamic acids LIX®1104, LIX®1104SM and the mixture of LIX®1104 and Versatic 10", Hydrometallurgy, 119-120: pp. 67-72, (2012).
19
[15] Sayar, N. A., Filiz, M., Sayar, A. A., "Extraction of Co(II) and Ni(II) from concentrated HCl solutions using Alamine 336", Hydrometallurgy, 96:
20
pp.148-153 (2009).
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[16] Lin, L., Jian-hong, W., Gen-Yi, W., Toyohisa, F., Atsushi, S., "Extraction studies of cobalt and nickel from chloride solution using PC88A", Trans. Nonferrous Met. Soc. China, 16: pp. 687-692, (2006).
22
[17] Zhu, Z., Zhang, W., Pranolo, Y., Cheng, C. Y., "Separation and recovery of copper, nickel, cobalt and zinc in chloride solutions by synergistic solvent extraction", Hydrometallurgy 127-128: pp. 1-7, (2012).
23
[18] Liu, Y., Lee, M., "Separation of Co and Ni from a chloride leach solutions of laterite ore by solvent extraction with extractant mixtures", J. Ind. Eng. Chem., 28: pp.322-327, (2015).
24
[19] Padhan, E., Sarangi, K., "Separation of molybdenum and cobalt from spent catalyst using Cyanex 272 and Cyanex 301", Int. J. Miner. Process 127: pp. 52-61, (2014).
25
[20] Cheng, C. Y., "Solvent extraction of nickel and cobalt with synergistic systems consisting of carboxylic acid and aliphatic hydroxyoxime", Hydrometallurgy, 84: pp. 109–117, (2006).
26
[21] Cheng, C. Y., Urbani, M. D., Davies, M. G., Pranolo, Y., Zhu, Z., "Recovery of nickel and cobalt from leach solutions of nickel laterites using a synergistic system consisting of Versatic 10 and Acorga CLX 50", Miner. Eng., 77: pp. 17-24, (2015).
27
[22] Shan, Z., Hui-Ping, H., Ji-Yuan, L., Fang, H., "The Coordination Structure of the Extracted Cobalt(II) Complex with a Synergistic Mixture Containing Lix63 and Versatic10", J. Chinese Chem. Soc., 64: pp. 833-842, (2017).
28
[23] Takahashi, V. C. I., Junior, A. B. B., Espinosa, D. C. R., Tenório, J. A. S., "Enhancing cobalt recovery from Li-ion batteries using grinding treatment prior to the leaching and solvent extraction process". J. Environ. Chem. Eng., 8: pp. 103801, (2020).
29
[24] Wang, L. Y., Lee, M. S., "Synergistic extraction of Co(II) over Ni(II) from chloride solutions by a mixture of Cyanex 301 and LIX 63", Geosystem Eng. 20: pp. 311-317, (2017).
30
[25] Wellens, S., Thijs, B., Möller, C., Binnemans, K., "Separation of cobalt and nickel by solvent extraction with two mutually immiscible ionic liquids", Phys. Chem. Chem. Phys., 15: pp. 9663-9669, (2013).
31
[26] Cole, P. M., "The introduction of solvent-extraction steps during upgrading of a cobalt refinery", Hydrometallurgy, 64: pp. 69-77, (2002).
32
[27] Coll, M. T., Fortuny, A., Kedari, C. S., Sastre, A. M., "Studies on the extraction of Co(II) and Ni(II) from aqueous chloride solutions using Primene
33
JMT-Cyanex272 ionic liquid extractant", Hydrometallurgy, 125-126: pp. 24-28, (2012).
34
[28] Asadollahzadeh, M., Torkaman, R., Torab-Mostaedi, M., Hemmati, A., "Enhancing Cerium Recovery from Leaching Solution of Glass Polishing Powder Waste Using Imidazolium Ionic Liquid", Waste Biomass Valori., Article in Press, DOI:10.1007/s12649-020-01070-w, (2020).
35
[29] Shakib, B., Torkaman, R., Torab-Mostaedi, M., Asadollahzadeh, M., "The Performance of Pulsed Scale-up Column for Permeable of Selenium and Tellurium Ions to Organic Phase, Case Study: Disc and Doughnut Structure", Chem. Eng. Process, Article in Press, DOI:10.1016/j.cep.2020.108042: 108042, (2020).
36
[30] Asadollahzadeh, M., Torkaman, R., Torab-Mostaedi, M., "Coupling minimum cross-entropy model with experimental data to determine the drop size distribution for lanthanum extraction in ARDC column", Sep. Sci. Technol. Article in Press, DOI: 10.1080/01496395.2020.1754429, (2020).
37
[31] Asadollahzadeh, M., Torkaman, R., Torab-Mostaedi, M., "Continuous Extraction of Europium(III) by
38
Ionic Liquid in the Rotating Disk Column with
39
an Asymmetrical Structure Aimed at the Evaluation of Reactive Mass Transfer", ACS Omega, 5:
40
pp. 18700-18709, (2020).
41
[32] Shakib, B., Torab-Mostaedi, M., Outokesh, M., Asadollahzadeh, M., "Direct extraction of Mo(VI) from sulfate solution by synergistic extractants in the rotation column", Chinese J. Chem. Eng., 28:
42
pp. 445-455, (2020).
43
[33] Asadollahzadeh, M., Torkaman, R., Torab-Mostaedi, M., "Study on the feasibility of using a pilot plant Scheibel extraction column for the extraction and separation of lanthanum and cerium from aqueous solution", Korean J. Chem. Eng. 37: pp. 322-331, (2020).
44
[34] Asadollahzadeh, M., Torkaman, R., Torab-Mostaedi, M., Moazami, F., "Estimation of Performance with the Two Truncated Probability Density Functions, Case Study: Using Mixco Column to Extract Samarium and Gadolinium", Sep. Sci. Technol . Article in Press, DOI: 10.1080/01496395.2020. 1757713, (2020).
45
[35] Shakib, B., Torkaman, R., Torab-Mostaedi, M., Asadollahzadeh, M., "Revealing mass transfer and hydrodynamic effects in a PRDC column by using the integration of extraction and separation for molybdenum and tungsten ions from aqueous solution", Chem. Pap., Article in Press, DOI:10.1007/s11696-020-01241-y, (2020).
46
[36] Shakib, B., Torkaman, R., Torab-Mostaedi, M., Asadollahzadeh, M. "Exact hydrodynamic description of pilot plant Oldshue-Rushton contactor: a case study with the introduction of selenium and tellurium into reaction system", Int. J. Environ. Anal. Chem., Article in Press, DOI:10.1080/03067319.2020. 1781103, (2019).
47
[37] Wellens, S., Thijs, B., Binnemans, K., "An environmentally friendlier approach to hydrometallurgy: highly selective separation of cobalt from nickel by solvent extraction with undiluted phosphonium ionic liquids", Green. Chem., 14:
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pp. 1657-1665, (2012).
49
[38] Cheng, C.Y., Barnard, K.R., Zhang, W., Robinson, D.J., "Synergistic Solvent Extraction of Nickel and Cobalt: A Review of Recent Developments", Solvent Ext. Ion. Exch., 29: pp. 719-754, (2011).
50
[39] Zhang, Y., Tang, J., Liu, S., Hu, F., Liu, M., Jin, W., Hu, J., "Extraction separation of copper and cobalt dependent on intermolecular interaction between Cyanex302 and Cyphos IL101", Sep. Purif. Technol. 240: pp. 116625, (2020).
51
[40] Huang, T., Wang, Y. X., Hu, H. P., Hu, F.,
52
Luo, Y. Q., Luo, S. J., "Phase separation in
53
solvent extraction of cobalt from acidic sulfate solution using synergistic mixture containing dinonylnaphthalene sulfonic acid and 2-ethylhexyl 4-pyridinecarboxylate ester", Trans. Nonferrous. Met. Soc. 29: pp. 1107-1116, (2019).
54
[41] Rafighi, P., Yaftian, M. R., Noshiranzadeh, N., "Solvent extraction of cobalt(II) ions; cooperation of oximes and neutral donors", Sep. Purif. Technol., 75: pp. 32-38, (2010).
55
[42] Zhao, J. M., Shen, X. Y., Deng, F. L., Wang, F. C., Wu, Y., Liu, H. Z., "Synergistic extraction and separation of valuable metals from waste cathodic material of lithium ion batteries using Cyanex272 and PC-88A", Sep. Purif. Technol. 78: pp. 345-351, (2011).
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ORIGINAL_ARTICLE
مطالعۀ تجربی جذب کربن دیاکسید در حلال مونواتانولآمین با استفاده از روش سطح پاسخ
گاز دیاکسید کربن یکی از اصلیترین آلایندههای محیط زیست است که با تغییر آب و هوا میتواند خسارات جبرانناپذیری وارد کند؛ از این رو حل این معضل نیاز به توجهی جدی دارد. در حال حاضر جذب شیمیایی CO2 با محلولهای آبی آلکانو آمینی متداولترین روش تجاری جداسازی با بازدهی بالا در صنعت است. در میان روشهای مختلف حذف گاز دیاکسیدکربن از گازهای دودکش، فرایند جذب واکنشدار با حلال آبی مونواتانولآمین (MEA)، مهمترین گزینه در کاربردهای صنعتی سالهای اخیر بوده است. در این تحقیق از حلال MEA برای بررسی میزان جذب CO2 استفاده شده است. محدودۀ تجربی مؤلفههای مطالعه شونده شامل دمای 60-20 درجۀ سلسیوس، فشار 5/9-5/3 بار و غلظت حلال5/8-5/2 درصد وزنی است. بارگیری و درصد جذب CO2 بهترتیب در محلول آبی MEA در محدودۀ 615/0-270/0 و 65/48-81/17 درصد به دست آمده است. برای تجزیۀ نتایج از الگوی چندجملهای درجۀ دو با روش سطح پاسخ (RSM) استفاده شده است. همچنین برای یافتن بیشینۀ مقدار بارگیری و درصد جذب تحت شرایط بهینه، بهینهسازی عددی به کار گرفته شده است. در شرایط بهینه بیشینۀ مقدار بارگیری و درصد جذب بهترتیب برابر 552/0 و 17/44 تخمین زده شده است.
https://www.ijche.ir/article_119022_70f322e2d40b0ab9696c24c8b8a6c226.pdf
2020-10-22
43
54
دیاکسیدکربن
محلول آبی مونو اتانول آمین
روش سطح پاسخ
امیرحسین
محسنی
amir_mohseni2112@yahoo.com
1
دانشجوی دانشگاه علم و صنعت ایران
AUTHOR
احد
قائمی
aghaemi@iust.ac.ir
2
هیات علمی دانشگاه علم و صنعت ایران
LEAD_AUTHOR
[1] Apergis, N., Aye, G. C., Barros, C. P., Gupta, R., Wanke, P., "Energy efficiency of selected OECD countries: A slacks based model with undesirable outputs", Energy Economics, 51: pp. 45-53, (2015).
1
[2] Tian, H., Lu, C., Ciais, P., Michalak, A. M., Canadell, J. G., Saikawa, E., Yang, J., "The terrestrial biosphere as a net source of greenhouse gases to the atmosphere", Nature, 531(7593), pp. 225-228, (2016).
2
[3] Rinprasertmeechai, S., Chavadej, S., Rangsunvigit, P., Kulprathipanja, S., "Carbon dioxide removal from flue gas using amine-based hybrid solvent absorption", International Journal of Chemical and Biological Engineering, 6: pp. 296-300, (2012).
3
[4] Ghaemi, A., Shahhosseini, S., Maragheh, M. G., "Nonequilibrium dynamic modeling of carbon dioxide absorption by partially carbonated ammonia solutions", Chemical Engineering Journal, 149(1-3): pp. 110-117, (2009).
4
[5] Norouzbahari, S., Shahhosseini, S., Ghaemi, A., "Modeling of CO2 loading in aqueous solutions of piperazine: Application of an enhanced artificial neural network algorithm", Journal of Natural Gas Science and Engineering, 24: pp. 18-25, (2015).
5
[6] Khajeh Amiri, M., Ghaemi, A., Arjomandi, H., "Experimental, Kinetics and Isotherm Modeling of Carbon Dioxide Adsorption with 13X Zeolite in a fixed bed column". Iranian Journal of Chemical Engineering (IJChE), 16(1): pp. 54-64, (2019).
6
[7] Pashaei, H., Ghaemi, A., Nasiri, M., "Experimental investigation of CO2 removal using Piperazine solution in a stirrer bubble column", International Journal of Greenhouse Gas Control, 63: pp. 226-240, (2017).
7
[8] Hayer, H., Ghaemi, A., "Modeling of simultaneous heat and mass transfer in hollow fiber membranes", International Journal of Chemical Modeling, 6(1):
8
pp. 25, (2014).
9
[9] Ghaemi, A., Behroozi, A. H., "Comparison of hydroxide-based adsorbents of Mg (OH)2 and Ca (OH)2 for CO2 capture: utilization of response surface methodology, kinetic, and isotherm modeling", Greenhouse Gases: Science and Technology, (2020).
10
[10] Taheri, F. S., Ghaemi, A., Maleki, A., Shahhosseini, S., "High CO2 adsorption on amine-functionalized improved mesoporous silica nanotube as an
11
eco-friendly nanocomposite". Energy & Fuels, 33(6): pp. 5384-5397, (2019).
12
[11] Mohammad, N. K., Ghaemi, A., Tahvildari, K., "Hydroxide modified activated alumina as an adsorbent for CO2 adsorption: experimental and modeling". International Journal of Greenhouse Gas Control, 88: pp. 24-37, (2019).
13
[12] Khajeh, M., Ghaemi, A., "Exploiting response surface methodology for experimental modeling and optimization of CO2 adsorption onto NaOH-modified nanoclay montmorillonite", Journal of Environmental Chemical Engineering, 8(2): pp. 103663, (2020).
14
[13] Pashaei, H., Ghaemi, A., Nasiri, M., Karami, B., "Experimental modeling and optimization of CO2 absorption into piperazine solutions using RSM-CCD methodology", ACS omega, 5(15): pp. 8432-8448, (2020).
15
[14] Fashi, F., Ghaemi, A., Behroozi, A. H., "Piperazine impregnation on Zeolite 13X as a novel adsorbent for CO2 capture: experimental and modeling", Chemical Engineering Communications, pp. 1-17, (2020).
16
[15] Lee, D. H., Choi, W. J., Moon, S. J., Ha, S. H., Kim, I. G., Oh, K. J., "Characteristics of absorption and regeneration of carbon dioxide in aqueous 2-amino-
17
2-methyl-1-propanol/ammonia solutions", Korean Journal of Chemical Engineering, 25(2): pp. 279-284, (2008).
18
[16] Aronu, U. E., Gondal, S., Hessen, E. T.,
19
Haug-Warberg, T., Hartono, A., Hoff, K. A., Svendsen, H. F., "Solubility of CO2 in 15, 30, 45 and 60 mass% MEA from 40 to 120 C and model representation using the extended UNIQUAC framework", Chemical Engineering Science, 66(24): pp. 6393-6406, (2011).
20
[17] Gomes, J., Santos, S., Bordado, J., "Choosing amine-based absorbents for CO2 capture". Environmental technology, 36(1): pp. 19-25, (2015).
21
[18] ذوالفقاری، س.، هنرور، د.، ب.، "بررسی تأثیر غلظت، دما و فشار بر حلالیت گاز CO2 بر محلول MEA"، پنجمین کنفرانس بینالمللی پزوهشهای کاربردی در شیمی و مهندسی شیمی با تأکید بر فناوریهای بومی ایران، 11–1، (1396).
22
[19] Ghaemi, A., "Mass transfer and thermodynamic modeling of carbon dioxide absorption into MEA aqueous solution", Polish Journal of Chemical Technology, 19(3): pp. 75-82, (2017).
23
[20] Ghaemi, A., "Mass Transfer Modeling of CO2 Absorption into Blended MDEA-MEA Solution". Journal of Chemical and Petroleum Engineering, 54(1): pp. 111-128, (2020).
24
[21] Karnwiboon, K., Saiwan, C., Idem, R., Supap, T., "Tontiwachwuthikul, P., Solvent Extraction of Degradation Products in Amine Absorption Solution for CO2 Capture in Flue Gases from Coal Combustion: Effect of Amines", Energy Procedia, 114: pp.1980-1985, (2017).
25
[22] Neagu, M., Onuţu, I., "The Study of CO2 Removal by Aqueous Solution of Methyldiethanolamine through Absorption Process", Petroleum-Gas University of Ploiesti Bulletin, Technical Series, 68(2), (2016).
26
[23] Gupta, M., Coyle, I., "Thambimuthu, K., CO2 capture technologies and opportunities in Canada", In 1st Canadian CC&S Technology Roadmap Workshop, 18: 19, (2003).
27
[24] Saeidi, M., Ghaemi, A., Tahvildari, K., Derakhshi, P., "Exploiting response surface methodology (RSM) as a novel approach for the optimization of carbon dioxide adsorption by dry sodium hydroxide", Journal of The Chinese Chemical Society, 65(12):
28
pp. 1465-1475, (2018).
29
[25] Kim, Y. E., Lim, J. A., Jeong, S. K., Yoon, Y. I., Bae, S. T., Nam, S. C., "Comparison of carbon dioxide absorption in aqueous MEA, DEA, TEA, and AMP solutions", Bulletin of the Korean Chemical Society, 34(3): pp. 783-787, (2013).
30
[26] Amiri, M., Shahhosseini, S., Ghaemi, A., "Optimization of CO2 capture process from simulated flue gas by dry regenerable alkali metal carbonate based adsorbent using response surface methodology", Energy & Fuels, 31(5):
31
pp. 5286-5296, (2017).
32
[27] Leonzio, G., "Optimization through response surface methodology of a reactor producing methanol by the hydrogenation of carbon dioxide", Processes, 5(4):
33
p. 62, (2017).
34
[28] Mourabet, M., El Rhilassi, A., El Boujaady, H., Bennani-Ziatni, M., Taitai, A., "Use of response surface methodology for optimization of fluoride adsorption in an aqueous solution by Brushite", Arabian Journal of Chemistry, 10: pp. S3292-S3302, (2017).
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ORIGINAL_ARTICLE
مروری بر روشهای تخلیص دیانای: سامانههای میکروفلوئیدیک
استخراج زیستمولکولها و بررسیهای ژنتیکی آن در زمینۀ پزشکی و پزشکی قانونی اهمیت بسیار زیادی دارد؛ اما با این حال محدودیتهای آن از قبیل حساسیت، ماهیت کار، هزینۀ بالا، نیاز به تکنسینهای بسیار ماهر و نیاز به خودکارسازی و قابلیت حمل سامانه، ازنظر تشخیص با فناوریهای موجود، رفع نشده است. نیاز به ادغام روشهای آمادهسازی و تشخیص نمونه وجود دارد؛ برای رفع این محدودیتها، بیشتر مطالعات بر بهبود فناوریهای تشخیص تمرکز کردهاند که پیشرفتهای چشمگیری حاصل شده است؛ یکی از این فناوریها، میکروفلوئیدیک است. ویژگیهای قانعکنندهای، مانند خودکارسازی در تهیۀ نمونه و قابلیت کار در حجم کمی از نمونه، همچنین به حداقل رساندن مصرف، هزینه و زمان پردازش حلالها از برتریهای این فناوری در استخراج دیانای و پروتئین است. عملکرد میکروکانالها در استخراج به سطح ویژۀ در دسترس انتقال جرم بستگی دارد که خود نیز به الگوی جریان تولیدشده در اتصالات ورودی میکروکانالها وابسته است. رایجترین الگوها، موازی، لختهای و قطرهای است که به مؤلفههای عملیاتی مانند سرعت جریان، خواص فیزیکی، هندسۀ میکروکانال و مواد سازندۀ آن وابستهاند. یک الگوی جریان علاوه بر اینکه باید سطح ویژۀ زیادی را فراهم کند در عین حال باید بهگونهای باشد که فازها پس از استخراج بهسرعت از یکدیگر جدا شوند. مهمترین هدف این مقاله بررسی روشهای مرسوم در سامانههای ناپیوستهای است که قابلیت پیادهسازی در میکروفلوئیدیک را داشتهاند.نتیجۀ بررسی این شد که سه روش استخراج بر پایۀ سیلیکا، اتصال الکترواستاتیک و کروماتوگرافی تمایل ژل سازگاری بسیار بالایی با این سامانهها دارند.
https://www.ijche.ir/article_119024_b972edff851929eaa00f0a92e2f1ac41.pdf
2020-10-22
55
80
میکروفلوئیدیک
زیستمولکول
دیانای
پروتئین
فرشاد
راجی
farshadraji77@gmail.com
1
دانشجوی ارشد مهندسی شیمی گرایش فرایندهای جداسازی دانشگاه علم و صنعت ایران
AUTHOR
احمد
رهبرکلیشمی
ahmadrahbar@iust.ac.ir
2
دانشیار دانشگاه علم و صنعت
LEAD_AUTHOR
[1] Xu, C., Xie, T., "Review of microfluidic liquid–liquid extractors", Industrial and Engineering Chemistry Research, 56: pp. 7593-7622, (2017).
1
[2] Artyukhin, A. B., Woo, Y. H., "DNA extraction method with improved efficiency and specificity using DNA methyltransferase and "click" chemistry", Analytical Biochemistry, 425: pp. 169-174, (2012).
2
[3] Dahm, R., "Friedrich Miescher and the discovery of DNA", Developmental biology, 278: pp. 274-288, (2005).
3
[4] Dahm, R., "Discovering DNA: Friedrich Miescher and the early years of nucleic acid research", Human genetics, 122: pp. 565-581, (2008).
4
[5] Sia, S. K., Kricka, L., "Microfluidics and
5
point-of-care testing", Lab on a Chip, 8:
6
pp. 1982-1983, (2008).
7
[6] Ruiz-Fuentes, J. L., Díaz, A., Entenza, A. E., Frion, Y., Suárez, O., Torres, P., de Armas, Y., Acosta, L., "Comparison of four DNA extraction methods for the detection of Mycobacterium leprae from Ziehl–Neelsen-stained microscopic slides", International journal of mycobacteriology, 4: pp. 284-289, (2015).
8
[7] Ayoib, A., Hashim, U., Gopinath, S. C. B., Arshad, M. K., "DNA extraction on bio-chip: history and preeminence over conventional and solid-phase extraction methods", Applied Microbiology and Biotechnology, 101: pp. 8077–8088, (2017).
9
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ORIGINAL_ARTICLE
بررسی روشها و عوامل مؤثر بر ساخت نانوذرات اکسید مس تکظرفیتی به فرم پایدار
در سالهای اخیر، از نانوذرات اکسید مس تکظرفیتی (Cu2O) بهدلیل داشتن خواصی منحصر به فرد، به شکلهای گوناگونی در صنایع مختلف استفاده شده است. بهدلیل اهمیت و کاربرد فراوان آن، روشهای متداول همنهشت این نانوذره که بیشتر از راه کاهش شیمیایی و ایجاد رسوب در یک محیط قلیایی آبی انجام میشود، در چهار گروه رسوبدهی، سولوترمال/ هیدروترمال، سونوشیمی و الکتروشیمی بررسی شده است. خواص و ویژگیها، پایداری و همچنین میزان عملکرد این نانوذره به نحوۀ ساخت و مؤلفههای مؤثر بر اندازه، ساختار، شکل، خلوص و پایداری آن بستگی دارد؛ لذا تأثیر عواملی مانند نوع سورفکتانت و پیشماده، عامل پوششدهنده و کاهنده، دما و زمان واکنش، سرعت همزدن مواد اولیه و غلظت حلال مصرفی بررسی شده است؛ با افزایش غلظت عامل کاهنده، سرعت همزدن، غلظت پیشماده و حلال تا حد بهینه، اندازۀ ذرات همنهشتی کوچکتر میشود.
https://www.ijche.ir/article_119025_bc4131ea55a6e113e0d92db5ad9d9baa.pdf
2020-10-22
81
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اکسید مس (I)
رسوبدهی
هیدروترمال
آیسان
ضرغام
aysanzargham93@gmail.com
1
دانشکده نانوفناوری، دانشگاه سمنان
AUTHOR
جواد
مقدم
moghaddam@znu.ac.ir
2
دانشگاه زنجان، دانشکده مهندسی، گروه مهندسی مواد
AUTHOR
نرجس
کرامتی
narjeskeramati@semnan.ac.ir
3
دانشکده نانوفناوری، دانشگاه سمنان
LEAD_AUTHOR
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